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Finally, the free induction decay (FID) of the X nuclei is detected, typically with 1 H decoupling. Cross-polarization ( CP ), originally published as proton-enhanced nuclear induction spectroscopy ( PENIS ) [ 1 ] [ 2 ] is a solid-state nuclear magnetic resonance (ssNMR) technique to transfer nuclear magnetization from different types of nuclei ...
COSMO [1] [2] (COnductor-like Screening MOdel) is a calculation method for determining the electrostatic interaction of a molecule with a solvent. COSMO is a dielectric continuum model [1] [3] [4] [5] (a.k.a. continuum solvation model). These models can be used in computational chemistry to model solvation effects. COSMO has become a popular ...
Insensitive nuclei enhancement by polarization transfer (INEPT) is a signal enhancement method used in NMR spectroscopy. It involves the transfer of nuclear spin polarization from spins with large Boltzmann population differences to nuclear spins of interest with lower Boltzmann population differences. [ 1 ]
Polarization can be used to filter out unwanted signals, such as jamming. If a jammer and receiver do not have the same polarization, the jamming signal will incur a loss that reduces its effectiveness. The four basic polarizations are linear horizontal, linear vertical, right-hand circular, and left-hand circular.
any real, finite, level of XPD instead manifests itself as a partial recombination between the two signals, so that the receivers observe an interference due to the cross-polarization leakage. Some of the factors causing such cross-polarization interference are listed in Polarization-Division Multiplexing. Polarization-Division Communication System
The polarizable continuum model (PCM) is a commonly used method in computational chemistry to model solvation effects. If it is necessary to consider each solvent molecule as a separate molecule, the computational cost of modeling a solvent-mediated chemical reaction would grow prohibitively high.
Consider the case of interaction of two perpendicularly polarized waves in nonlinear media with cubic nonlinearity. [1] The equations describing the self phase modulation of the fundamental wave A and the generation of new wave perpendicularly polarized wave B in condition that |B| << |A| (i.e. when the depletion of the fundamental wave is neglected, self and cross phase modulation of wave B ...
One consequence of this natural polarization of molecules is that 1,3- and 1,5- heteroatom substituted carbon skeletons are extremely easy to synthesize (Aldol reaction, Claisen condensation, Michael reaction, Claisen rearrangement, Diels-Alder reaction), whereas 1,2-, 1,4-, and 1,6- heteroatom substitution patterns are more difficult to access ...