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The ideal gas law, also called the general gas equation, is the equation of state of a hypothetical ideal gas. It is a good approximation of the behavior of many gases under many conditions, although it has several limitations.
All perfect gas models are ideal gas models in the sense that they all follow the ideal gas equation of state. However, the idea of a perfect gas model is often invoked as a combination of the ideal gas equation of state with specific additional assumptions regarding the variation (or nonvariation) of the heat capacity with temperature.
At present, there is no single equation of state that accurately predicts the properties of all substances under all conditions. An example of an equation of state correlates densities of gases and liquids to temperatures and pressures, known as the ideal gas law, which is roughly accurate for weakly polar gases at low pressures and moderate temperatures.
The ideal gas law is the equation of state for an ideal gas, given by: = where P is the pressure; V is the volume; n is the amount of substance of the gas (in moles) T is the absolute temperature; R is the gas constant, which must be expressed in units consistent with those chosen for pressure, volume and temperature.
A scalar field can be viewed as a sort of perfect fluid with equation of state = ˙ ˙ + (), where ˙ is the time-derivative of and () is the potential energy. A free ( V = 0 {\displaystyle V=0} ) scalar field has w = 1 {\displaystyle w=1} , and one with vanishing kinetic energy is equivalent to a cosmological constant: w = − 1 {\displaystyle ...
The equation of state for an ideal or perfect gas is the ideal gas law and reads P V = n R T , {\displaystyle PV=nRT,} where P is the pressure, V is the volume, n is amount of gas (in mol units), R is the universal gas constant , 8.314 J/(mol K), and T is the temperature.
where P is the pressure, V is the volume, N is the number of gas molecules, k B is the Boltzmann constant (1.381×10 −23 J·K −1 in SI units) and T is the absolute temperature. These equations are exact only for an ideal gas, which neglects various intermolecular effects (see real gas). However, the ideal gas law is a good approximation for ...
The van der Waals equation, named for its originator, the Dutch physicist Johannes Diderik van der Waals, is an equation of state that extends the ideal gas law to include the non-zero size of gas molecules and the interactions between them (both of which depend on the specific substance).