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Since the heat of combustion of these elements is known, the heating value can be calculated using Dulong's Formula: HHV [kJ/g]= 33.87m C + 122.3(m H - m O ÷ 8) + 9.4m S where m C , m H , m O , m N , and m S are the contents of carbon, hydrogen, oxygen, nitrogen, and sulfur on any (wet, dry or ash free) basis, respectively.
This is an example of exothermic reaction and demonstrates the large amount of energy released in the combustion of alcohols. The reaction of burning of ethanol is represented by the following chemical equation: C 2 H 5 OH(g) + 3O 2 (g) = 2CO 2 (g) + 3H 2 O(g).
Ethanol (also called ethyl alcohol, grain alcohol, drinking alcohol, or simply alcohol) is an organic compound with the chemical formula CH 3 CH 2 OH. It is an alcohol, with its formula also written as C 2 H 5 OH, C 2 H 6 O or EtOH, where Et stands for ethyl. Ethanol is a volatile, flammable, colorless liquid with a characteristic wine-like ...
A dish of ethanol aflame. Various alcohols are used as fuel for internal combustion engines.The first four aliphatic alcohols (methanol, ethanol, propanol, and butanol) are of interest as fuels because they can be synthesized chemically or biologically, and they have characteristics which allow them to be used in internal combustion engines.
Excess volume of the mixture of ethanol and water (volume contraction) Heat of mixing of the mixture of ethanol and water Vapor–liquid equilibrium of the mixture of ethanol and water (including azeotrope) Solid–liquid equilibrium of the mixture of ethanol and water (including eutecticum) Miscibility gap in the mixture of dodecane and ethanol
Ethanol is less acutely toxic. [27] All alcohols are mild skin irritants. [25] Methanol and ethylene glycol are more toxic than other simple alcohols. Their metabolism is affected by the presence of ethanol, which has a higher affinity for liver alcohol dehydrogenase. In this way, methanol will be excreted intact in urine. [28] [29] [30]
Ethanol burning with its spectrum depicted. In the study of combustion, the adiabatic flame temperature is the temperature reached by a flame under ideal conditions. It is an upper bound of the temperature that is reached in actual processes.
However, non-radical intermediates are stable and are produced in incomplete combustion. An example is acetaldehyde produced in the combustion of ethanol. An intermediate in the combustion of carbon and hydrocarbons, carbon monoxide, is of special importance because it is a poisonous gas, but also economically useful for the production of syngas.