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By the equipartition theorem, internal energy per mole of gas equals c v T, where T is absolute temperature and the specific heat at constant volume is c v = (f)(R/2). R = 8.314 J/(K mol) is the universal gas constant, and "f" is the number of thermodynamic (quadratic) degrees of freedom, counting the number of ways in which energy can occur.
The term phase is sometimes used as a synonym for state of matter, but it is possible for a single compound to form different phases that are in the same state of matter. For example, ice is the solid state of water, but there are multiple phases of ice with different crystal structures, which are formed at different pressures and temperatures.
Solid: A solid holds a definite shape and volume without the need of a container. The particles are held very close to each other. Amorphous solid: A solid in which there is no far-range order of the positions of the atoms. Crystalline solid: A solid in which atoms, molecules, or ions are packed in regular order.
In contrast to thermotropic liquid crystals, these lyotropics have another degree of freedom of concentration that enables them to induce a variety of different phases. A compound that has two immiscible hydrophilic and hydrophobic parts within the same molecule is called an amphiphilic molecule. Many amphiphilic molecules show lyotropic liquid ...
In many scientific fields, the degrees of freedom of a system is the number of parameters of the system that may vary independently. For example, a point in the plane has two degrees of freedom for translation : its two coordinates ; a non-infinitesimal object on the plane might have additional degrees of freedoms related to its orientation .
Familiar examples are the melting of ice or the boiling of water (the water does not instantly turn into vapor, but forms a turbulent mixture of liquid water and vapor bubbles). Yoseph Imry and Michael Wortis showed that quenched disorder can broaden a first-order transition. That is, the transformation is completed over a finite range of ...
The polarized form of the water molecule, H + OH −, is also called hydron hydroxide by IUPAC nomenclature. [106] Water substance is a rare term used for H 2 O when one does not wish to specify the phase of matter (liquid water, water vapor, some form of ice, or a component in a mixture) though the term water is also used with this general ...
The number of degrees of freedom F (also called the variance) is the number of independent intensive properties, i.e., the largest number of thermodynamic parameters such as temperature or pressure that can be varied simultaneously and independently of each other. [5] An example of a one-component system (C = 1) is a pure chemical.