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Lime softening (also known as lime buttering, lime-soda treatment, or Clark's process) [1] is a type of water treatment used for water softening, which uses the addition of limewater (calcium hydroxide) to remove hardness (deposits of calcium and magnesium salts) by precipitation.
Water softening is the removal of calcium, magnesium, and certain other metal cations in hard water. The resulting soft water requires less soap for the same cleaning effort, as soap is not wasted bonding with calcium ions.
To avoid scaling in water cooled heat exchangers, water is treated by lime and or soda ash to remove the water hardness. The following chemical reactions take place in lime soda softening process which precipitates the calcium and magnesium salts as calcium carbonate and magnesium hydroxide which have very low solubility in water.
He became known for the discovery of the phosphate of soda, and the process of lime softening of hard water the 'Clark process'. A Clark degree (°Clark) of water hardness is defined as one grain (64.8 mg) of CaCO 3 per Imperial gallon (4.55 litres) of water, equivalent to 14.254 ppm. and 10^5 parts of water
Precipitative softening: [4]: 13.12–13.58 Water rich in hardness (calcium and magnesium ions) is treated with lime (calcium oxide) and/or soda-ash (sodium carbonate) to precipitate calcium carbonate out of solution utilising the common-ion effect. Electrodeionization: [9] Water is passed between a positive electrode and a negative electrode.
Soda lime canister used in anaesthetic machines to act as a carbon dioxide scrubber. Soda lime, a mixture of sodium hydroxide (NaOH) and calcium oxide (CaO), is used in granular form within recirculating breathing environments like general anesthesia and its breathing circuit, submarines, rebreathers, and hyperbaric chambers and underwater habitats.
However, there is an equilibrium between dissolved calcium bicarbonate and dissolved calcium carbonate as represented by the chemical equation Ca 2+ + 2 HCO − 3 ⇌ Ca 2+ + CO 2− 3 + CO 2 + H 2 O. Note that CO 2 is dissolved in the water. Carbon dioxide dissolved in water (aq) tends to equilibrate with carbon dioxide in the gaseous state (g):
An aqueous solution containing 120 mg NaHCO 3 (baking soda) per litre of water will contain 1.4285 mmol/l of bicarbonate, since the molar mass of baking soda is 84.007 g/mol. This is equivalent in carbonate hardness to a solution containing 0.71423 mmol/L of (calcium) carbonate, or 71.485 mg/L of calcium carbonate (molar mass 100.09 g/mol).