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[1] [2] [3] A more fundamental statement was later labelled as the zeroth law after the first three laws had been established. The zeroth law of thermodynamics defines thermal equilibrium and forms a basis for the definition of temperature: if two systems are each in thermal equilibrium with a third system, then they are in thermal equilibrium ...
The molar heat capacity is the heat capacity per unit amount (SI unit: mole) of a pure substance, and the specific heat capacity, often called simply specific heat, is the heat capacity per unit mass of a material. Heat capacity is a physical property of a substance, which means that it depends on the state and properties of the substance under ...
Quantities, Units and Symbols in Physical Chemistry, also known as the Green Book, is a compilation of terms and symbols widely used in the field of physical chemistry. It also includes a table of physical constants , tables listing the properties of elementary particles , chemical elements , and nuclides , and information about conversion ...
The SI unit for heat capacity of an object is joule per kelvin (J/K or J⋅K −1). Since an increment of temperature of one degree Celsius is the same as an increment of one kelvin, that is the same unit as J/°C. The heat capacity of an object is an amount of energy divided by a temperature change, which has the dimension L 2 ⋅M⋅T −2 ...
In chemistry, heat amounts were often measured in calories. Confusingly, there are two common units with that name, respectively denoted cal and Cal: the small calorie (gram-calorie, cal) is 4.184 J exactly. It was originally defined so that the specific heat capacity of liquid water would be 1 cal/(°C⋅g).
Chemical thermodynamics is the study of the interrelation of heat and work with chemical reactions or with physical changes of state within the confines of the laws of thermodynamics. Chemical thermodynamics involves not only laboratory measurements of various thermodynamic properties, but also the application of mathematical methods to the ...
The molar heat capacity of a substance has the same dimension as the heat capacity of an object; namely, L 2 ⋅M⋅T −2 ⋅Θ −1, or M(L/T) 2 /Θ. (Indeed, it is the heat capacity of the object that consists of an Avogadro number of molecules of the substance.)
The corresponding expression for the ratio of specific heat capacities remains the same since the thermodynamic system size-dependent quantities, whether on a per mass or per mole basis, cancel out in the ratio because specific heat capacities are intensive properties. Thus: