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13 C NMR Spectrum of DMSO-d 6. Pure deuterated DMSO shows no peaks in 1 H NMR spectroscopy and as a result is commonly used as an NMR solvent. [2] However commercially available samples are not 100% pure and a residual DMSO-d 5 1 H NMR signal is observed at 2.50ppm (quintet, J HD =1.9Hz). The 13 C chemical shift of DMSO-d 6 is 39.52ppm (septet ...
Commercial chloroform-d does, however, still contain a small amount (0.2% or less) of non-deuterated chloroform; this results in a small singlet at 7.26 ppm, known as the residual solvent peak, which is frequently used as an internal chemical shift reference. In carbon-13 NMR spectroscopy, the sole carbon in deuterated chloroform shows a ...
For these reasons, 13 C-NMR spectra are usually recorded with proton NMR decoupling. Couplings between carbons can be ignored due to the low natural abundance of 13 C. Hence in contrast to typical proton NMR spectra, which show multiplets for each proton position, carbon NMR spectra show a single peak for each chemically non-equivalent carbon ...
Structure and properties Index of refraction, [1] n D: 1.4795 at 20 °C 1.4787 at 21 °C Abbe number? Dielectric constant, [2] ε r: 48 ε 0 at 20 °C Bond strength? Bond length? Bond angle? Magnetic susceptibility? Surface tension [2] 43 dyn/cm at 20 °C Viscosity: 2.14 mPa·s [2] at 20 °C 1.1 mPa·s [1] at 27 °C
Carbon satellites in physics and spectroscopy, are small peaks that can be seen shouldering the main peaks in the nuclear magnetic resonance (NMR) spectrum.These peaks can occur in the NMR spectrum of any NMR active atom (e.g. 19 F or 31 P NMR) where those atoms adjoin a carbon atom (and where the spectrum is not 13 C-decoupled, which is usually the case).
Structure of DMSO (red = O, yellow = S) as determined by X-ray crystallography of PdBr 2 (bipy)·DMSO. [2] Sulfoxides feature relatively short S–O distances. In DMSO, the S–O distance is 1.531 Å. The sulfur center is pyramidal; the sum of the angles at sulfur is about 306°. [3]
Dimethyl sulfoxide (DMSO) is an organosulfur compound with the formula (CH 3) 2 S O.This colorless liquid is the sulfoxide most widely used commercially. It is an important polar aprotic solvent that dissolves both polar and nonpolar compounds and is miscible in a wide range of organic solvents as well as water.
Deuterated solvents are a group of compounds where one or more hydrogen atoms are substituted by deuterium atoms. These isotopologues of common solvents are often used in nuclear magnetic resonance spectroscopy .