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4 bind to strongly electrophilic metal centers of the type use in some catalytic reactions. [ 2 ] [ 3 ] Tetrafluoroborate and hexafluorophosphate anions are coordinating toward highly electrophilic metal ions, such as cations containing Zr(IV) centers, which can abstract fluoride from these anions.
The EWG removes electron density from a π system, making it less reactive in this type of reaction, [2] [3] and therefore called deactivating groups. EDGs and EWGs also determine the positions (relative to themselves) on the aromatic ring where substitution reactions are most likely to take place.
An example of a simple chain reaction is the thermal decomposition of acetaldehyde (CH 3 CHO) to methane (CH 4) and carbon monoxide (CO). The experimental reaction order is 3/2, [4] which can be explained by a Rice-Herzfeld mechanism. [5] This reaction mechanism for acetaldehyde has 4 steps with rate equations for each step :
Also acid ionization constant or acidity constant. A quantitative measure of the strength of an acid in solution expressed as an equilibrium constant for a chemical dissociation reaction in the context of acid-base reactions. It is often given as its base-10 cologarithm, p K a. acid–base extraction A chemical reaction in which chemical species are separated from other acids and bases. acid ...
The following list includes the metallic elements of the first six periods. It is mostly based on tables provided by NIST. [9] [10] However, not all sources give the same values: there are some differences between the precise values given by NIST and the CRC Handbook of Chemistry and Physics. In the first six periods this does not make a ...
Salt metathesis reaction; Salt-free reduction; Scavenger resin; Screaming jelly babies; SEA Native Peptide Ligation; Self-assembling peptide; Semiclassical transition state theory; Shiina esterification; Side reaction; Single displacement reaction; Small molecule sensors; Solid-state reaction route; Spin-forbidden reactions; Stripping reaction ...
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Strict weak orders are very closely related to total preorders or (non-strict) weak orders, and the same mathematical concepts that can be modeled with strict weak orderings can be modeled equally well with total preorders. A total preorder or weak order is a preorder in which any two elements are comparable. [7]