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Liquid water is densest, essentially 1.00 g/cm 3, at 4 °C and begins to lose its density as the water molecules begin to form the hexagonal crystals of ice as the freezing point is reached. This is due to hydrogen bonding dominating the intermolecular forces, which results in a packing of molecules less compact in the solid.
Freezing is a phase transition in which a liquid turns into a solid when its temperature is lowered below its freezing point. [ 1 ] [ 2 ] For most substances, the melting and freezing points are the same temperature; however, certain substances possess differing solid-liquid transition temperatures.
The increase observed for water from 0 °C (32 °F) to 3.98 °C (39.16 °F) and for a few other liquids [d] is described as negative thermal expansion. Regular, hexagonal ice is also less dense than liquid water—upon freezing, the density of water decreases by about 9%. [36] [e]
Up to 99.63 °C (the boiling point of water at 0.1 MPa), at this pressure water exists as a liquid. Above that, it exists as water vapor. Note that the boiling point of 100.0 °C is at a pressure of 0.101325 MPa (1 atm), which is the average atmospheric pressure.
Freezing [1] or frost occurs when the air temperature falls below the freezing point of water (0 °C, 32 °F, 273 K). This is usually measured at the height of 1.2 metres above the ground surface. This is usually measured at the height of 1.2 metres above the ground surface.
The 0 °C isotherm under normal conditions. The freezing level, or 0 °C (zero-degree) isotherm, represents the altitude in which the temperature is at 0 °C (the freezing point of water) in a free atmosphere (i.e. allowing reflection of the sun by snow, icing conditions, etc.).
The difference of temperatures between the freezing- and boiling-points of water under standard atmospheric pressure shall be called 100 degrees. (The same increment as the Celsius scale) Thomson's best estimates at the time were that the temperature of freezing water was 273.7 K and the temperature of boiling water was 373.7 K. [33]
The latent heat of melting is much smaller, partly because liquid water near 0 °C also contains a significant number of hydrogen bonds. By contrast, the structure of ice II is hydrogen-ordered, which helps to explain the entropy change of 3.22 J/mol when the crystal structure changes to that of ice I.