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R-22 use is being phased out in developing countries, where it is largely used for air conditioning applications. R-22 is prepared from chloroform: HCCl 3 + 2 HF → HCF 2 Cl + 2 HCl. An important application of R-22 is as a precursor to tetrafluoroethylene. This conversion involves pyrolysis to give difluorocarbene, which dimerizes: [3]
R-410A was invented and patented by Allied Signal (now Honeywell) in 1991. [5] Other producers around the world have been licensed to manufacture and sell R-410A. [6] R-410A was successfully commercialized in the air conditioning segment by a combined effort of Carrier Corporation, Emerson Climate Technologies, Inc., Copeland Scroll Compressors (a division of Emerson Electric Company), and ...
Being phased out: A widely used hydrochlorofluorocarbon (HCFC) and powerful greenhouse gas with a GWP equal to 1810. Worldwide production of R-22 in 2008 was about 800 Gg per year, up from about 450 Gg per year in 1998. R-438A (MO-99) is a R-22 replacement. [71] R-123 HCFC-123 CHCl 2 CF 3: 2,2-Dichloro-1,1,1-trifluoroethane: 292 79 US phase-out
According to ASHRAE standard 34, the R-number of a chemical refrigerant is assigned systematically according to its molecular structure and has between two and four digits. If there are carbon -carbon multiple bonds , there are four digits in all: the number of these bonds is the first digit and the number of carbon atoms minus one (C-1) is next.
Chlorodifluoromethane (R-22 or HCFC-22), a type of Freon. [9] [10] Dichlorodifluoromethane (R-12 or CFC-12), the most commonly used Freon brand refrigerant prior to its ban in many countries in 1996 and total ban in 2010. 1,1,1,2-Tetrafluoroethane (R-134a or HFC-134a), one of the main replacements for the formerly widespread R-12.
The phasing out of CFC and HCFC refrigerants (e.g., HCFC-22, also known as R22) due to global warming concerns has helped to spur innovations in cooling technologies. [23] [24] Natural refrigerants such as carbon dioxide and propane (), as well as R-410A, have become attractive replacements for air conditioning and refrigeration applications.
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Because of its reduced global warming potential (GWP), R-454B is intended to be an alternative to refrigerant R-410A in new equipment. [2] [3] [4] R-454B has a GWP of 466, which is 78 percent lower than R-410A's GWP of 2088. [2] R-454B is non-toxic and mildly flammable, with an ASHRAE safety classification of A2L. In the United States, it is ...