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The kinetic theory of gases deals not only with gases in thermodynamic equilibrium, but also very importantly with gases not in thermodynamic equilibrium. This means using Kinetic Theory to consider what are known as "transport properties", such as viscosity, thermal conductivity, mass diffusivity and thermal diffusion.
The general equation can then be written as [6] = + + (),. where the "force" term corresponds to the forces exerted on the particles by an external influence (not by the particles themselves), the "diff" term represents the diffusion of particles, and "coll" is the collision term – accounting for the forces acting between particles in collisions.
The Maxwell–Boltzmann distribution is a result of the kinetic theory of gases, which provides a simplified explanation of many fundamental gaseous properties, including pressure and diffusion. [3] The Maxwell–Boltzmann distribution applies fundamentally to particle velocities in three dimensions, but turns out to depend only on the speed ...
In other words, the configuration of particle A in state 1 and particle B in state 2 is different from the case in which particle B is in state 1 and particle A is in state 2. This assumption leads to the proper (Boltzmann) statistics of particles in the energy states, but yields non-physical results for the entropy, as embodied in the Gibbs ...
s-particle distribution functions were introduced in classical statistical mechanics by J. Yvon in 1935. [6] The BBGKY hierarchy of equations for s-particle distribution functions was written out and applied to the derivation of kinetic equations by Bogoliubov in the article received in July 1945 and published in 1946 in Russian [2] and in ...
First, Vlasov argues that the standard kinetic approach based on the Boltzmann equation has difficulties when applied to a description of the plasma with long-range Coulomb interaction. He mentions the following problems arising when applying the kinetic theory based on pair collisions to plasma dynamics:
Kinetic theory may refer to: Kinetic theory of matter: A general account of the properties of matter, including solids liquids and gases, based around the idea that heat or temperature is a manifestation of atoms and molecules in constant agitation. Kinetic theory of gases, an account of gas properties in terms of motion and interaction of ...
However, when he relates it to a particle of mass m moving at a velocity u which is the result of a frictional force governed by Stokes's law, he finds [()] = = =, where μ is the viscosity coefficient, and a is the radius of the particle. Associating the kinetic energy / with the thermal energy RT/N, the expression for the mean squared ...