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Ruthenium(III) fluoride can be obtained from the reduction of ruthenium(V) fluoride by iodine at 250 °C: [3] [4] 5 RuF 5 + I 2 → 5 RuF 3 + 2 IF 5 Properties
[4] In 2009, Data.gov was established to improve public access to high value, machine-readable datasets generated by the Executive Branch of the Federal Government. [5] In 2019, the OPEN Government Data Act ordered agencies to share data that could be used to evaluate the effectiveness of their programs and to guide policymaking. Various ...
Tris(acetonitrile)cyclopentadienylruthenium hexafluorophosphate is an organoruthenium compound with the formula [(C 5 H 5)Ru(NCCH 3) 3]PF 6, abbreviated [CpRu(NCMe) 3]PF 6. It is a yellow-brown solid that is soluble in polar organic solvents. The compound is a salt consisting of the hexafluorophosphate anion and the cation [CpRu(NCMe) 3] +.
Ruthenium pentafluoride is the inorganic compound with the empirical formula RuF 5.This green volatile solid has rarely been studied but is of interest as a binary fluoride of ruthenium, i.e. a compound containing only Ru and F.
Ruthenium(V) fluoride (ruthenium pentafluoride), RuF 5; Ruthenium(VI) fluoride (ruthenium hexafluoride), RuF 6 This page was last edited on 21 ...
RuF 4 in the solid state is polymeric, with a three-dimensional structure of corrugated layers containing RuF 6 octahedra joined by shared fluorine atoms. The crystalline structure is similar to that of vanadium tetrafluoride and is monoclinic, space group P2 1 /n, with lattice constants a = 560.7 pm, b = 494.6 pm, and c =514.3 pm, β = 121.27°.
Ruthenium hexafluoride was discovered by American radiochemists in 1961, soon after the discovery of technetium hexafluoride. [3] It is made by a direct reaction of ruthenium metal in a gas stream of fluorine and argon at 400–450 °C. The yields of this reaction are less than 10%. [4] Ru + 3 F 2 → RuF 6
Ruthenium(III) acetylacetonate is a coordination complex with the formula Ru(O 2 C 5 H 7) 3. O 2 C 5 H 7 − is the ligand called acetylacetonate. This compound exists as a dark red solid that is soluble in most organic solvents. [3] It is used as a precursor to other compounds of ruthenium.