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In chemical thermodynamics, an endergonic reaction (from Greek ἔνδον (endon) 'within' and ἔργον (ergon) 'work'; also called a heat absorbing nonspontaneous reaction or an unfavorable reaction) is a chemical reaction in which the standard change in free energy is positive, and an additional driving force is needed to perform this ...
Large particles are more energetically favorable since, continuing with this example, more atoms are bonded to 6 neighbors and fewer atoms are at the unfavorable surface. As the system tries to lower its overall energy, molecules on the surface of a small particle (energetically unfavorable, with only 3 or 4 or 5 bonded neighbors) will tend to ...
For example, consider two extended dislocations: DB = Dγ + γB and BC = Bδ + δC. When they meet, it is more energetically favorable to form a single dislocation, DC = DB + BC = Dγ + γB + Bδ + δC = Dγ + γδ + δC. The trailing partials of each extended dislocation now form a stair-rod partial.
Thermochemistry is the study of the heat energy which is associated with chemical reactions and/or phase changes such as melting and boiling. A reaction may release or absorb energy, and a phase change may do the same. Thermochemistry focuses on the energy exchange between a system and its surroundings in the form of heat. Thermochemistry is ...
Practically, enthalpies, not free energy, are used to determine whether a reaction is favorable or unfavorable, because ∆H° is easier to measure and T∆S° is usually too small to be of any significance (for T < 100 °C). A reaction with ∆H°<0 is called exothermic reaction while one with ∆H°>0 is endothermic.
Anabolism usually involves reduction and decreases entropy, making it unfavorable without energy input. [6] The starting materials, called the precursor molecules, are joined using the chemical energy made available from hydrolyzing ATP, reducing the cofactors NAD + , NADP + , and FAD , or performing other favorable side reactions. [ 7 ]
The equilibrium width is thus partially determined by the stacking-fault energy. When the SFE is high the dissociation of a full dislocation into two partials is energetically unfavorable, and the material can deform either by dislocation glide or cross-slip. Lower SFE materials display wider stacking faults and have more difficulties for cross ...
The total free energy change of a reaction is independent of the activation energy however. Physical and chemical reactions can be either exergonic or endergonic, but the activation energy is not related to the spontaneity of a reaction. The overall reaction energy change is not altered by the activation energy.
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