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Low-spin [Fe(NO 2) 6] 3− crystal field diagram. The Δ splitting of the d orbitals plays an important role in the electron spin state of a coordination complex. Three factors affect Δ: the period (row in periodic table) of the metal ion, the charge of the metal ion, and the field strength of the complex's ligands as described by the spectrochemical series.
A high multiplicity state is therefore the same as a high-spin state. The lowest-energy state with maximum multiplicity usually has unpaired electrons all with parallel spin. Since the spin of each electron is 1/2, the total spin is one-half the number of unpaired electrons, and the multiplicity is the number of unpaired electrons + 1.
Spin State may refer to: Spin quantum number , a quantum number Spin states (d electrons) , the potentials for high-spin and low-spin configurations of d electrons in transition metal complexes.
Examples of atoms in singlet, doublet, and triplet states. In quantum mechanics, a triplet state, or spin triplet, is the quantum state of an object such as an electron, atom, or molecule, having a quantum spin S = 1. It has three allowed values of the spin's projection along a given axis m S = −1, 0, or +1, giving the name "triplet".
Rotating a spin-2 particle 180° can bring it back to the same quantum state, and a spin-4 particle should be rotated 90° to bring it back to the same quantum state. The spin-2 particle can be analogous to a straight stick that looks the same even after it is rotated 180°, and a spin-0 particle can be imagined as sphere, which looks the same ...
A pair of electrons in a spin singlet state has S = 0, and a pair in the triplet state has S = 1, with m S = −1, 0, or +1. Nuclear-spin quantum numbers are conventionally written I for spin, and m I or M I for the z-axis component. The name "spin" comes from a geometrical spinning of the electron about an axis, as proposed by Uhlenbeck and ...
A more complicated case is given (in bra–ket notation) by the singlet state, which exemplifies quantum entanglement: | = (| | ), which involves superposition of joint spin states for two particles with spin 1/2. The singlet state satisfies the property that if the particles' spins are measured along the same direction then either the spin of ...
The spin transition is an example of transition between two electronic states in molecular chemistry. The ability of an electron to transit from a stable to another stable (or metastable ) electronic state in a reversible and detectable fashion, makes these molecular systems appealing in the field of molecular electronics .
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