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In organic chemistry, a radical-substitution reaction is a substitution reaction involving free radicals as a reactive intermediate. [1] The reaction always involves at least two steps, and possibly a third. In the first step called initiation (2,3), a free radical is created by homolysis.
Free-radical substitution, for instance free-radical halogenation and autoxidation. Free-radical addition reactions; Intramolecular free radical reactions (substitution or addition) such as the Hofmann–Löffler reaction or the Barton reaction; Free radical rearrangement reactions are rare compared to rearrangements involving carbocations and ...
Chain propagation: A radical reacts with a non-radical to produce a new radical species; Chain termination: Two radicals react with each other to create a non-radical species; In a free-radical addition, there are two chain propagation steps. In one, the adding radical attaches to a multiply-bonded precursor to give a radical with lesser bond ...
Substitution reactions in organic chemistry are classified either as electrophilic or nucleophilic depending upon the reagent involved, whether a reactive intermediate involved in the reaction is a carbocation, a carbanion or a free radical, and whether the substrate is aliphatic or aromatic. Detailed understanding of a reaction type helps to ...
In organic chemistry, free-radical halogenation is a type of halogenation. This chemical reaction is typical of alkanes and alkyl-substituted aromatics under application of UV light. The reaction is used for the industrial synthesis of chloroform (CHCl 3), dichloromethane (CH 2 Cl 2), and hexachlorobutadiene. It proceeds by a free-radical chain ...
Radical-nucleophilic aromatic substitution or S RN 1 in organic chemistry is a type of substitution reaction in which a certain substituent on an aromatic compound is replaced by a nucleophile through an intermediary free radical species: Radical-nucleophilic aromatic substitution overview
Free-radical intermediate is stabilized by hyperconjugation; adjacent occupied sigma C–H orbitals donate into the electron-deficient radical orbital. A new method of anti-Markovnikov addition has been described by Hamilton and Nicewicz, who utilize aromatic molecules and light energy from a low-energy diode to turn the alkene into a cation ...
Pages in category "Free radical reactions" The following 25 pages are in this category, out of 25 total. ... Radical fluorination; Radical substitution;