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Kinetic theory may refer to: Kinetic theory of matter: A general account of the properties of matter, including solids liquids and gases, based around the idea that heat or temperature is a manifestation of atoms and molecules in constant agitation. Kinetic theory of gases, an account of gas properties in terms of motion and interaction of ...
The kinetic theory of gases is a simple ... molecules' strike against a solid body in constant succession it ... to the kinetic molecular theory of ...
Boltzmann's kinetic theory of gases was one of the first attempts to explain macroscopic properties, such as pressure and temperature, in terms of the behaviour of individual atoms and molecules. Although many chemists were already accepting the existence of atoms and molecules, the broader physics community took some time to embrace this view.
The (Newtonian) kinetic energy of a particle of mass m, velocity v is given by = | | = (+ +), where v x, v y and v z are the Cartesian components of the velocity v.Here, H is short for Hamiltonian, and used henceforth as a symbol for energy because the Hamiltonian formalism plays a central role in the most general form of the equipartition theorem.
The general equation can then be written as [6] = + + (),. where the "force" term corresponds to the forces exerted on the particles by an external influence (not by the particles themselves), the "diff" term represents the diffusion of particles, and "coll" is the collision term – accounting for the forces acting between particles in collisions.
The kinetic theory of gases applies to the classical ideal gas, which is an idealization of real gases. In real gases, there are various effects (e.g., van der Waals interactions , vortical flow, relativistic speed limits, and quantum exchange interactions ) that can make their speed distribution different from the Maxwell–Boltzmann form.
Kinetic theory of gases [ edit ] In the kinetic theory of gases , the mean free path of a particle, such as a molecule , is the average distance the particle travels between collisions with other moving particles.
In a solid, constituent particles (ions, atoms, or molecules) are closely packed together. The forces between particles are so strong that the particles cannot move freely but can only vibrate. As a result, a solid has a stable, definite shape, and a definite volume. Solids can only change their shape by an outside force, as when broken or cut.