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For a fixed mass of an ideal gas kept at a fixed temperature, pressure and volume are inversely proportional. [2] Boyle's law is a gas law, stating that the pressure and volume of a gas have an inverse relationship. If volume increases, then pressure decreases and vice versa, when the temperature is held constant.
The volume of gas increases proportionally to absolute temperature and decreases inversely proportionally to pressure, approximately according to the ideal gas law: = where: p is the pressure; V is the volume; n is the amount of substance of gas (moles) R is the gas constant, 8.314 J·K −1 mol −1
Isotherms of an ideal gas for different temperatures. The curved lines are rectangular hyperbolae of the form y = a/x. They represent the relationship between pressure (on the vertical axis) and volume (on the horizontal axis) for an ideal gas at different temperatures: lines that are farther away from the origin (that is, lines that are nearer to the top right-hand corner of the diagram ...
The laws describing the behaviour of gases under fixed pressure, volume, amount of gas, and absolute temperature conditions are called gas laws.The basic gas laws were discovered by the end of the 18th century when scientists found out that relationships between pressure, volume and temperature of a sample of gas could be obtained which would hold to approximation for all gases.
The ideal gas equation can be rearranged to give an expression for the molar volume of an ideal gas: = = Hence, for a given temperature and pressure, the molar volume is the same for all ideal gases and is based on the gas constant: R = 8.314 462 618 153 24 m 3 ⋅Pa⋅K −1 ⋅mol −1, or about 8.205 736 608 095 96 × 10 −5 m 3 ⋅atm⋅K ...
The molar volume of gases around STP and at atmospheric pressure can be calculated with an accuracy that is usually sufficient by using the ideal gas law. The molar volume of any ideal gas may be calculated at various standard reference conditions as shown below: V m = 8.3145 × 273.15 / 101.325 = 22.414 dm 3 /mol at 0 °C and 101.325 kPa
Gas stoichiometry deals with reactions solely involving gases, where the gases are at a known temperature, pressure, and volume and can be assumed to be ideal gases. For gases, the volume ratio is ideally the same by the ideal gas law, but the mass ratio of a single reaction has to be calculated from the molecular masses of the reactants and ...
Specific volume is inversely proportional to density. If the density of a substance doubles, its specific volume, as expressed in the same base units, is cut in half. If the density drops to 1/10 its former value, the specific volume, as expressed in the same base units, increases by a factor of 10.