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Abiological nitrogen fixation describes chemical processes that fix (react with) N 2, usually with the goal of generating ammonia. The dominant technology for abiological nitrogen fixation is the Haber process, which uses iron-based heterogeneous catalysts and H 2 to convert N 2 to NH 3. This article focuses on homogeneous (soluble) catalysts ...
The Haber process, [1] also called the Haber–Bosch process, is the main industrial procedure for the production of ammonia. [2] [3] It converts atmospheric nitrogen (N 2) to ammonia (NH 3) by a reaction with hydrogen (H 2) using finely divided iron metal as a catalyst:
The Birkeland–Eyde process was one of the competing industrial processes in the beginning of nitrogen-based fertilizer production. It is a multi-step nitrogen fixation reaction that uses electrical arcs to react atmospheric nitrogen (N 2 ) with oxygen (O 2 ), ultimately producing nitric acid (HNO 3 ) with water. [ 1 ]
High nitrogen purity: PSA nitrogen generator plants allow production of high-purity nitrogen from air, which membrane systems are unable to provide – up to 99.9995% nitrogen. But in most cases they do not produce more than 98.8% nitrogen with the remainder being argon that is not separated from the nitrogen by the usual PSA process.
The fixation of nitrogen by lightning is a very similar natural occurring process. The possibility that atmospheric nitrogen reacts with certain chemicals was first observed by Desfosses in 1828. He observed that mixtures of alkali metal oxides and carbon react with nitrogen at high temperatures.
The history of the Haber process begins with the invention of the Haber process at the dawn of the twentieth century. The process allows the economical fixation of atmospheric dinitrogen in the form of ammonia, which in turn allows for the industrial synthesis of various explosives and nitrogen fertilizers, and is probably the most important industrial process developed during the twentieth ...
A nitrogen generator Bottle of 4Å molecular sieves. Pressure swing adsorption provides separation of oxygen or nitrogen from air without liquefaction. The process operates around ambient temperature; a zeolite (molecular sponge) is exposed to high pressure air, then the air is released and an adsorbed film of the desired gas is released.
The Frank–Caro process, also called cyanamide process, is the nitrogen fixation reaction of calcium carbide with nitrogen gas in a reactor vessel at about 1,000 °C. The reaction is exothermic and self-sustaining once the reaction temperature is reached. Originally the reaction took place in large steel cylinders with an electrical resistance ...