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  2. Tris(pentafluorophenyl)borane - Wikipedia

    en.wikipedia.org/wiki/Tris(pentafluorophenyl)borane

    Tris(pentafluorophenyl)borane, sometimes referred to as "BCF", is the chemical compound (C 6 F 5) 3 B.It is a white, volatile solid. The molecule consists of three pentafluorophenyl groups attached in a "paddle-wheel" manner to a central boron atom; the BC 3 core is planar.

  3. Cycloisomerization - Wikipedia

    en.wikipedia.org/wiki/Cycloisomerization

    The activation barrier of isomerization of 1,3–hexadiene through a [1,5]–shift is 41 Kcal mol–1 and is expected to increase with conjugation to the ester, thus uncatalyzed isomerization is unlikely. [11] This provides the advantage of bypassing a high barrier of activation, providing access to previously unobtainable IMDA derivatives.

  4. Bromopentafluorobenzene - Wikipedia

    en.wikipedia.org/wiki/Bromopentafluorobenzene

    Bromopentafluorobenzene is an organofluorine compound with the formula C 6 F 5 Br. It is a colorless liquid that is used to prepare pentafluophenyl compounds. These syntheses typically proceed via the intermediacy of C 6 F 5 Li or the Grignard reagent. [1]

  5. Isomerization - Wikipedia

    en.wikipedia.org/wiki/Isomerization

    In chemistry, isomerization or isomerisation is the process in which a molecule, polyatomic ion or molecular fragment is transformed into an isomer with a different chemical structure. [1] Enolization is an example of isomerization, as is tautomerization .

  6. Beckmann rearrangement - Wikipedia

    en.wikipedia.org/wiki/Beckmann_rearrangement

    In the third step, an isomerization step protonates the nitrogen atom leading to the amide. The Beckmann rearrangement mechanism The same computation with a hydroxonium ion and 6 molecules of water has the same result, but when the migrating substituent is a phenyl group, the mechanism favors the formation of an intermediate three-membered π ...

  7. Penex - Wikipedia

    en.wikipedia.org/wiki/Penex

    Ideally, the isomerization catalyst converts normal pentane (nC5) to isopentane (iC5) and normal hexane (nC6) to 2,2- and 2,3-dimethylbutane. ... This page was last ...

  8. Boranylium ions - Wikipedia

    en.wikipedia.org/wiki/Boranylium_ions

    Various representations of bonding in borenium ions. [2]A borenium ion is an inorganic cation with the chemical formula [BR 2 L] +In this class of molecules, the electron-deficient boron center has two valence electrons involved in sigma bonding with two ligands, while the third ligand is a two-electron donor such that the overall charge of the complex is +1. [1]

  9. Valence isomer - Wikipedia

    en.wikipedia.org/wiki/Valence_isomer

    There are many valence isomers one can draw for the C 6 H 6 formula benzene.Some were originally proposed for benzene itself before the actual structure of benzene was known.