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Mulliken charges arise from the Mulliken population analysis [1] [2] and provide a means of estimating partial atomic charges from calculations carried out by the methods of computational chemistry, particularly those based on the linear combination of atomic orbitals molecular orbital method, and are routinely used as variables in linear regression (QSAR [3]) procedures. [4]
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Ionic, or charged, structures for a given atom can be determined by assigning a charge to a molecule, and then following Rumer's method. For the case of butadiene, the 20 possible Rumer structures are shown, where 1 and 2 are the covalent structures, 3-14 are the monoionic structures, and 15-20 are the diionic structures.
The Mulliken electronegativity can only be calculated for an element whose electron affinity is known. Measured values are available for 72 elements, while approximate values have been estimated or calculated for the remaining elements. The Mulliken electronegativity of an atom is sometimes said to be the negative of the chemical potential. [14]
Millikan in 1891. Robert Andrews Millikan was born on March 22, 1868, in Morrison, Illinois. [6] He went to high school in Maquoketa, Iowa and received a bachelor's degree in the classics from Oberlin College in 1891 and his doctorate in physics from Columbia University in 1895 [11] – he was the first to earn a Ph.D. from that department.
Robert Sanderson Mulliken ForMemRS [1] (June 7, 1896 – October 31, 1986) was an American physical chemist, primarily responsible for the early development of molecular orbital theory, i.e. the elaboration of the molecular orbital method of computing the structure of molecules.
SADM in its carry bag SADM hard carrying case A U.S. Army Special Forces paratrooper conducts a high-altitude low-opening military freefall jump with an MK–54 SADM. The Special Atomic Demolition Munition (SADM), also known as the XM129 and XM159 Atomic Demolition Charges, [1] and the B54 bomb [2] was a nuclear man-portable atomic demolition munition (ADM) system fielded by the US military ...
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