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The Hamiltonian of a system represents the total energy of the system; that is, the sum of the kinetic and potential energies of all particles associated with the system. . The Hamiltonian takes different forms and can be simplified in some cases by taking into account the concrete characteristics of the system under analysis, such as single or several particles in the system, interaction ...
The value (,) of the Hamiltonian is the total energy of the system, in this case the sum of kinetic and potential energy, traditionally denoted T and V, respectively. Here p is the momentum mv and q is the space coordinate.
A Hamiltonian system is a dynamical system governed by Hamilton's equations. In physics , this dynamical system describes the evolution of a physical system such as a planetary system or an electron in an electromagnetic field .
In physics, action is a scalar quantity that describes how the balance of kinetic versus potential energy of a physical system changes with trajectory. Action is significant because it is an input to the principle of stationary action, an approach to classical mechanics that is simpler for multiple objects. [1]
The Hamiltonian for a system of discrete particles is a function of their generalized coordinates and conjugate momenta, and possibly, time. For continua and fields, Hamiltonian mechanics is unsuitable but can be extended by considering a large number of point masses, and taking the continuous limit, that is, infinitely many particles forming a continuum or field.
The stationary nuclei enter the problem only as generators of an electric potential in which the electrons move in a quantum mechanical way. Within this framework the molecular Hamiltonian has been simplified to the so-called clamped nucleus Hamiltonian, also called electronic Hamiltonian, that acts only on functions of the electronic coordinates.
Action angles result from a type-2 canonical transformation where the generating function is Hamilton's characteristic function (not Hamilton's principal function ).Since the original Hamiltonian does not depend on time explicitly, the new Hamiltonian (,) is merely the old Hamiltonian (,) expressed in terms of the new canonical coordinates, which we denote as (the action angles, which are the ...
where "H" and "S" label observables in Heisenberg and Schrödinger picture respectively, H is the Hamiltonian and [·,·] denotes the commutator of two operators (in this case H and A). Taking expectation values automatically yields the Ehrenfest theorem , featured in the correspondence principle .