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Titration (also known as titrimetry [1] and volumetric analysis) is a common laboratory method of quantitative chemical analysis to determine the concentration of an identified analyte (a substance to be analyzed). A reagent, termed the titrant or titrator, [2] is prepared as a standard solution of known concentration and volume.
The term also has two other, conflicting meanings. In titration, the titer is the ratio of actual to nominal concentration of a titrant, e.g. a titer of 0.5 would require 1/0.5 = 2 times more titrant than nominal. This is to compensate for possible degradation of the titrant solution.
Bromatometry is a titration process in which the bromination of a chemical indicator is observed. [ 1 ] Potassium bromate alone can be used for the analysis of organoarsenicals .
The first instrumental analysis was flame emissive spectrometry developed by Robert Bunsen and Gustav Kirchhoff who discovered rubidium (Rb) and caesium (Cs) in 1860. [4] Most of the major developments in analytical chemistry took place after 1900. During this period, instrumental analysis became progressively dominant in the field.
Thus, one standard solution is needed (e.g. HCl) in the direct titration, while two are needed (e.g. HCl and NaOH) in the back-titration. One of the suitable indicators for these titration reactions is Tashiro's indicator. [3] In practice, this analysis is largely automated; specific catalysts accelerate the decomposition. Originally, the ...
Although KF is a destructive analysis, the sample quantity is small and is typically limited by the accuracy of weighing. For example, in order to obtain an accuracy of 1% using a scale with the typical accuracy of 0.2 mg, the sample must contain 20 mg water, which is e.g. 200 mg for a sample with 10% water.
In analytical chemistry, a standard solution (titrant or titrator) is a solution containing an accurately known concentration.Standard solutions are generally prepared by dissolving a solute of known mass into a solvent to a precise volume, or by diluting a solution of known concentration with more solvent. [1]
In analytical chemistry, argentometry is a type of titration involving the silver(I) ion. Typically, it is used to determine the amount of chloride present in a sample. The sample solution is titrated against a solution of silver nitrate of known concentration. Chloride ions react with silver(I) ions to give the insoluble silver chloride: