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White liquor consists mainly of sodium hydroxide and sodium sulfide in water and is the active component in Kraft pulping. [1] White liquor also contains minor amounts of sodium carbonate, sodium sulfate, sodium thiosulfate, sodium chloride, calcium carbonate and other accumulated salts and non-process elements. These additional components are ...
In organic chemistry, a carbonate ester (organic carbonate or organocarbonate) is an ester of carbonic acid. This functional group consists of a carbonyl group flanked by two alkoxy groups. The general structure of these carbonates is R−O−C(=O)−O−R' and they are related to esters ( R−O−C(=O)−R' ), ethers ( R−O−R' ) and also to ...
Reaction mechanism for the Bucherer–Bergs reaction Following condensation of the carbonyl with the ammonium, the formed imine is attacked by the isocyanide to form the aminonitrile. Nucleophilic addition of aminonitrile to CO 2 leads to cyano-carbamic acid, which undergoes an intramolecular ring closing to 5-imino-oxazolidin-2-one.
Sodium carbonate is obtained as three hydrates and as the anhydrous salt: sodium carbonate decahydrate , Na 2 CO 3 ·10H 2 O, which readily effloresces to form the monohydrate. sodium carbonate heptahydrate (not known in mineral form), Na 2 CO 3 ·7H 2 O. sodium carbonate monohydrate (thermonatrite), Na 2 CO 3 ·H 2 O. Also known as crystal ...
A white mixture of sucrose and sodium bicarbonate will eventually turn black and the snake will grow about 15–50 centimetres (5.9–19.7 in) long after it is lit. [4] Three chemical reactions occur when the snake is lit. Sodium bicarbonate breaks down into sodium carbonate, water vapor, and carbon dioxide: [2] 2 NaHCO 3 (s) → Na 2 CO 3 (s ...
Fétizon oxidation is the oxidation of primary and secondary alcohols utilizing the compound silver(I) carbonate absorbed onto the surface of celite also known as Fétizon's reagent first employed by Marcel Fétizon in 1968. [1]
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One workaround to avoid this method is to reduce the carboxylic acid derivative all the way down to an alcohol, then oxidize the alcohol back to an aldehyde. Other alternatives include forming a thioester or a Weinreb amide, then reducing the new species to an aldehyde through the Fukuyama reduction or Weinreb reaction respectively, or using ...