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Sodium thiosulfate (sodium thiosulphate) is an inorganic compound with the formula Na 2 S 2 O 3 ·(H 2 O) x. Typically it is available as the white or colorless pentahydrate (x = 5), which is a white solid that dissolves well in water. The compound is a reducing agent and a ligand, and these properties underpin its applications. [2]
Anhydrous lithium hypochlorite is stable at room temperature; however, sodium hypochlorite is explosive as an anhydrous solid. [6] The pentahydrate (NaOCl·(H 2 O) 5) is unstable above 0 °C; [7] although the more dilute solutions encountered as household bleach are more stable. Potassium hypochlorite (KOCl) is known only in solution. [4]
Fixation is commonly achieved by treating the film or paper with a solution of thiosulfate salt. Popular salts are sodium thiosulfate—commonly called hypo—and ammonium thiosulfate—commonly used in modern rapid fixer formulae. [1] Fixation by thiosulfate involves these chemical reactions (X = halide, typically Br −): [2]
Thiosulfate (IUPAC-recommended spelling; sometimes thiosulphate in British English) is an oxyanion of sulfur with the chemical formula S 2 O 2− 3.Thiosulfate also refers to the compounds containing this anion, which are the salts of thiosulfuric acid, such as sodium thiosulfate Na 2 S 2 O 3 and ammonium thiosulfate (NH 4) 2 S 2 O 3.
Sodium hypochlorite is an alkaline inorganic chemical compound with the formula Na O Cl (also written as NaClO). It is commonly known in a dilute aqueous solution as bleach or chlorine bleach. [4] It is the sodium salt of hypochlorous acid, consisting of sodium cations (Na +) and hypochlorite anions (− OCl, also written as OCl − and ClO −).
To this a solution containing potassium iodide, sodium thiosulfate, and starch is added. There are two reactions occurring simultaneously in the solution. In the first, slow reaction, iodine is produced: H 2 O 2 + 2 I − + 2 H + → I 2 + 2 H 2 O. In the second, fast reaction, iodine is reconverted to two iodide ions by the thiosulfate:
It is a white, granular or crystalline solid, highly soluble in water, producing an alkaline solution. TSP is used as a cleaning agent, builder, lubricant, food additive, stain remover, and degreaser. [7] As an item of commerce TSP is often partially hydrated and may range from anhydrous Na 3 PO 4 to the dodecahydrate Na 3 PO 4 ·12H 2 O. Most ...
Sodium sulfate is a typical electrostatically bonded ionic sulfate. The existence of free sulfate ions in solution is indicated by the easy formation of insoluble sulfates when these solutions are treated with Ba 2+ or Pb 2+ salts: Na 2 SO 4 + BaCl 2 → 2 NaCl + BaSO 4. Sodium sulfate is unreactive toward most oxidizing or reducing agents.
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