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The formula for evaluating the drift velocity of charge carriers in a material of constant cross-sectional area is given by: [1] =, where u is the drift velocity of electrons, j is the current density flowing through the material, n is the charge-carrier number density, and q is the charge on the charge-carrier.
Recall that by definition, mobility is dependent on the drift velocity. The main factor determining drift velocity (other than effective mass) is scattering time, i.e. how long the carrier is ballistically accelerated by the electric field until it scatters (collides) with something that changes its direction and/or energy. The most important ...
In other words, the electrical mobility of the particle is defined as the ratio of the drift velocity to the magnitude of the electric field: =. For example, the mobility of the sodium ion (Na + ) in water at 25 °C is 5.19 × 10 −8 m 2 /(V·s) . [ 1 ]
The drift velocity is the average velocity of the charge carriers in the drift current. The drift velocity, and resulting current, is characterized by the mobility; for details, see electron mobility (for solids) or electrical mobility (for a more general discussion). See drift–diffusion equation for the way that the drift current, diffusion ...
The drift velocity then determines the electric current density and its relationship to E and is independent of the collisions. Drude calculated the average drift velocity from p = −eEτ where p is the average momentum, −e is the charge of the electron and τ is the average time between the collisions. Since both the momentum and the ...
In this case, the carrier density (in this context, also called the free electron density) can be estimated by: [5] n = N A Z ρ m m a {\displaystyle n={\frac {N_{\text{A}}Z\rho _{m}}{m_{a}}}} Where N A {\displaystyle N_{\text{A}}} is the Avogadro constant , Z is the number of valence electrons , ρ m {\displaystyle \rho _{m}} is the density of ...
The physical quantity ion mobility K is defined as the proportionality factor between an ion's drift velocity v d in a gas and an electric field of strength E. = After making the necessary adjustments to account for the n0 standard gas density, ion mobilities are often expressed as reduced mobilities.
Electrophoresis is the basis for analytical techniques used in biochemistry and bioinorganic chemistry to separate particles, molecules, or ions by size, charge, or binding affinity, either freely or through a supportive medium using a one-directional flow of electrical charge. [10]