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Osmium(I) iodide is a metallic grey solid produced by the reaction of osmium tetroxide and hydroiodic acid heated in a water bath for 48 hours in a carbon dioxide atmosphere. It is an amorphous compound. [34] Osmium(II) iodide is a black solid [35] produced by the reaction of osmium tetroxide and hydroiodic acid at 250 °C in nitrogen: [34]
Osmium (from Ancient Greek ὀσμή (osmḗ) 'smell') is a chemical element; it has symbol Os and atomic number 76. It is a hard, brittle, bluish-white transition metal in the platinum group that is found as a trace element in alloys, mostly in platinum ores. Osmium is the densest naturally occurring element.
The element name osmium is derived from osme, Greek for odor. OsO 4 is volatile: it sublimes at room temperature. It is soluble in a wide range of organic solvents. It is moderately soluble in water, with which it reacts reversibly to form osmic acid (see below). [9]
Dihydroxylation is the process by which an alkene is converted into a vicinal diol.Although there are many routes to accomplish this oxidation, the most common and direct processes use a high-oxidation-state transition metal (typically osmium or manganese).
Potassium ferricyanide (K 3 Fe(CN) 6) is the most commonly used stoichiometric oxidant for the reaction, and is the oxidant that comes in the commercially available AD-mix preparations. Additive: Citric acid: Osmium tetroxide is an electrophilic oxidant and as such reacts slowly with electron-deficient olefins.
Osmium(II) chloride or osmium ... Osmium(II) chloride does not react with hydrochloric acid and sulfuric acid. It reacts with CO at 220 °C: OsCl 2 + 3CO → Os(CO) 3 ...
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In chemistry, a reactivity series (or reactivity series of elements) is an empirical, calculated, and structurally analytical progression [1] of a series of metals, arranged by their "reactivity" from highest to lowest.