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Most of the carbonic acid then dissociates to bicarbonate and hydrogen ions. The bicarbonate buffer system is an acid-base homeostatic mechanism involving the balance of carbonic acid (H 2 CO 3), bicarbonate ion (HCO − 3), and carbon dioxide (CO 2) in order to maintain pH in the blood and duodenum, among other tissues, to support proper ...
In inorganic chemistry, bicarbonate (IUPAC-recommended nomenclature: hydrogencarbonate [2]) is an intermediate form in the deprotonation of carbonic acid. It is a polyatomic anion with the chemical formula H C O − 3. Bicarbonate serves a crucial biochemical role in the physiological pH buffering system. [3]
3 (i.e. the first acid dissociation constant for carbonic acid), K 2 is the equilibrium constant for the reaction HCO − 3 ⇌ H + + CO 2− 3 (i.e. the second acid dissociation constant for carbonic acid), and DIC is the (unchanging) total concentration of dissolved inorganic carbon in the system, i.e. [CO 2] + [HCO − 3] + [CO 2− 3].
Carbonic acid is the formal Brønsted–Lowry conjugate acid of the bicarbonate anion, stable in alkaline solution. The protonation constants have been measured to great precision, but depend on overall ionic strength I .
The bicarbonate buffer, consisting of a mixture of carbonic acid (H 2 CO 3) and a bicarbonate (HCO − 3) salt in solution, is the most abundant buffer in the extracellular fluid, and it is also the buffer whose acid-to-base ratio can be changed very easily and rapidly. [15]
Aqueous carbon dioxide reacts with water to form carbonic acid which is very unstable and will dissociate rapidly into hydronium and bicarbonate. Therefore, in seawater, dissolved inorganic carbon is commonly referred to as the collection of bicarbonate, carbonate ions, and dissolved carbon dioxide (CO 2, H 2 CO 3, HCO − 3, CO 2− 3).
The inorganic carbon species include carbon dioxide, carbonic acid, bicarbonate anion, and carbonate. [5] It is customary to express carbon dioxide and carbonic acid simultaneously as CO 2 *. C T is a key parameter when making measurements related to the pH of natural aqueous systems, [6] and carbon dioxide flux estimates.
Most carbonic acid then dissociates to bicarbonate and hydrogen ions. One of the buffer systems present in the body is the blood plasma buffering system. This is formed from , carbonic acid, working in conjunction with [HCO − 3], bicarbonate, to form the bicarbonate system. [10]