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In chemistry, a half reaction (or half-cell reaction) is either the oxidation or reduction reaction component of a redox reaction. A half reaction is obtained by considering the change in oxidation states of individual substances involved in the redox reaction. Often, the concept of half reactions is used to describe what occurs in an ...
Electron transfer reactions are central to myriad processes and properties in soils, and redox potential, quantified as Eh (platinum electrode potential relative to the standard hydrogen electrode) or pe (analogous to pH as -log electron activity), is a master variable, along with pH, that controls and is governed by chemical reactions and ...
In electrochemistry, the Nernst equation is a chemical thermodynamical relationship that permits the calculation of the reduction potential of a reaction (half-cell or full cell reaction) from the standard electrode potential, absolute temperature, the number of electrons involved in the redox reaction, and activities (often approximated by concentrations) of the chemical species undergoing ...
Since the Faraday constant can disappear from the equation, no need to calculate Δ r G o expressed in joule. A simple examination of a Latimer diagram can also indicate if a species will disproportionate in solution under the conditions for which the electrode potentials are given: if the potential to the right of the species is higher than ...
In chemistry, the oxygen reduction reaction refers to the reduction half reaction whereby O 2 is reduced to water or hydrogen peroxide. In fuel cells, the reduction to water is preferred because the current is higher. The oxygen reduction reaction is well demonstrated and highly efficient in nature. [1] [2]
Of the two half reactions, the oxidation step is the most demanding because it requires the coupling of 4 electron and proton transfers and the formation of an oxygen-oxygen bond. This process occurs naturally in plants photosystem II to provide protons and electrons for the photosynthesis process and release oxygen to the atmosphere, [ 1 ] as ...
In electrochemistry, cell notation or cell representation is a shorthand method of expressing a reaction in an electrochemical cell.. In cell notation, the two half-cells are described by writing the formula of each individual chemical species involved in the redox reaction across the cell, with all other common ions and inert substances being ignored.
The reaction quotient (Q r) of the half-reaction is the ratio between the chemical activities (a) of the reduced form (the reductant, a red) and the oxidized form (the oxidant, a ox). = Considering the 2 H + / H 2 redox couple:
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