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Cyclohexene oxide is produced in epoxidation reaction from cyclohexene. The epoxidation can take place either in a homogeneous reaction by peracids [2] or heterogeneous catalysis (e.g. silver and molecular oxygen). [3] [4] [5]
Cyclohexanone is produced by the oxidation of cyclohexane in air, typically using cobalt catalysts: [11]. C 6 H 12 + O 2 → (CH 2) 5 CO + H 2 O. This process forms cyclohexanol as a by-product, and this mixture, called "KA Oil" for ketone-alcohol oil, is the main feedstock for the production of adipic acid.
Cyclohexanone oxime can be prepared from the condensation reaction between cyclohexanone and hydroxylamine: [1] C 5 H 10 CO + H 2 NOH → C 5 H 10 C=NOH + H 2 O. Alternatively, another industrial route involves the reaction of cyclohexane with nitrosyl chloride, which is a free-radical reaction. This method is advantageous as cyclohexane is ...
Cyclohexylbenzene is a precursor to both phenol and cyclohexanone. [7] Hydration of cyclohexene gives cyclohexanol, which can be dehydrogenated to give cyclohexanone, a precursor to caprolactam. [8] The oxidative cleavage of cyclohexene gives adipic acid. Hydrogen peroxide is used as the oxidant in the presence of a tungsten catalyst. [9]
Cyclohexanone; Cyclohexene oxide; cis-3-Hexenal; Mesityl oxide; 3-Methyl-3-penten-2-one; Methylpentynol; Methylene tetrahydropyran This page was last edited on 1 ...
Isophorone undergoes reactions characteristic of an α,β-unsaturated ketone. Hydrogenation gives the cyclohexanone derivative. Epoxidation with basic hydrogen peroxide affords the oxide. [5] Isophorone is degraded by attack of hydroxyl radicals. [6]
Methanol oxidation employs a molybdenum oxide-based catalyst. Other large scale aldehydes and ketones are produced by autoxidation or hydrocarbons: benzaldehyde from toluene, acrolein from propylene, acetone from cumene, cyclohexanone from cyclohexanol. [2]
Cyclohexanone oxime; N-Formylpiperidine; Nylon 6 (repeating unit), or polycaprolactam This page was last edited on 5 March 2021, at 01:03 ...
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