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The tropospheric tabulation continues to 11,000 meters (36,089 ft), where the temperature has fallen to −56.5 °C (−69.7 °F), the pressure to 22,632 pascals (3.2825 psi), and the density to 0.3639 kilograms per cubic meter (0.02272 lb/cu ft). Between 11 km and 20 km, the temperature remains constant. [3] [4]
The pressure and temperature of the gas are directly proportional: As temperature increases, the pressure of the propane gas increases by the same factor. A simple consequence of this proportionality is that on a hot summer day, the propane tank pressure will be elevated, and thus propane tanks must be rated to withstand such increases in pressure.
The laws describing the behaviour of gases under fixed pressure, volume, amount of gas, and absolute temperature conditions are called gas laws.The basic gas laws were discovered by the end of the 18th century when scientists found out that relationships between pressure, volume and temperature of a sample of gas could be obtained which would hold to approximation for all gases.
Pressure as a function of the height above the sea level. There are two equations for computing pressure as a function of height. The first equation is applicable to the atmospheric layers in which the temperature is assumed to vary with altitude at a non null lapse rate of : = [,, ()] ′, The second equation is applicable to the atmospheric layers in which the temperature is assumed not to ...
where P is the pressure of the gas, V is the volume of the gas, and k is a constant for a particular temperature and amount of gas. Boyle's law states that when the temperature of a given mass of confined gas is constant, the product of its pressure and volume is also constant. When comparing the same substance under two different sets of ...
The August equation describes a linear relation between the logarithm of the pressure and the reciprocal temp. This assumes a temperature-independent heat of vaporization. The Antoine equation allows an improved, but still inexact description of the change of the heat of vaporization with the temperature.
The U.S. Standard Atmosphere is a static atmospheric model of how the pressure, temperature, density, and viscosity of the Earth's atmosphere change over a wide range of altitudes or elevations. The model, based on an existing international standard, was first published in 1958 by the U.S. Committee on Extension to the Standard Atmosphere, and ...
Thus from two such measurements of pressure and temperature one could determine and , and from these values calculate the expected critical pressure, temperature, and molar volume. Goodstein summarized this contribution of the van der Waals equation as follows: [28]