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CuCl + 3 P(C 6 H 5) 3 → CuCl[P(C 6 H 5) 3)] 3. CuCl also forms complexes with halides. For example H 3 O + CuCl 2 − forms in concentrated hydrochloric acid. [15] Chloride is displaced by CN − and S 2 O 3 2−. [12] Solutions of CuCl in HCl absorb carbon monoxide to form colourless complexes such as the chloride-bridged dimer [CuCl(CO)] 2.
CuCl 2 reacts with HCl or other chloride sources to form complex ions: the red [CuCl 3] − (found in potassium trichloridocuprate(II) K[CuCl 3]) (it is a dimer in reality, [Cu 2 Cl 6] 2−, a couple of tetrahedrons that share an edge), and the green or yellow [CuCl 4] 2− (found in potassium tetrachloridocuprate(II) K 2 [CuCl 4]). [5] [14] [15]
Copper(II) chloride (cupric chloride), CuCl 2, mineral name eriochalcite Index of chemical compounds with the same name This set index article lists chemical compounds articles associated with the same name.
In Cs 2 CuCl 4, CuCl 4 2− exhibits a distorted (flattened) tetrahedral geometry, whereas in [Pt(NH 3) 4][CuCl 4], it adopts a planar configuration. Green CuBr 3 − and violet CuBr 4 2− are also known. [9] Monovalent copper forms luminescent Cu n X n clusters (where X = Br, Cl, I), exhibiting diverse optical properties. [10] [11]
They are invariably Cu(I), although Cu(II) or even Cu(III) intermediates are invoked in some chemical reactions. Organic cuprates often have the idealized formulas [CuR 2] − and [CuR 3] 2−, both of which contain copper in an oxidation state of +1, where R is an alkyl or aryl. These reagents find use as nucleophilic alkylating reagents. [18]
Sodium copper tetrachloride – Na 2 CuCl 4; Sodium cyanate – NaCNO; Sodium cyanide – NaCN; Sodium dichromate – Na 2 Cr 2 O 7 ·2H 2 O; Sodium dioxide – NaO 2; Sodium dithionite – Na 2 S 2 O 4; Sodium ferrocyanide – Na 4 [Fe(CN) 6] Sodium fluoride – NaF; Sodium fluorosilicate – Na 2 [SiF 6] Sodium formate – HCOONa; Sodium ...
Copper is a chemical element with the symbol Cu (from Latin: cuprum) and the atomic number of 29. It is easily recognisable, due to its distinct red-orange color.Copper also has a range of different organic and inorganic salts, having varying oxidation states ranging from (0,I) to (III).
Atomic Energy of Canada Limited has demonstrated experimentally a CuCl electrolyzer in which hydrogen is produced electrolytically at the cathode and Cu(I) is oxidized to Cu(II) at the anode, thereby combining above steps 1 and 4 to eliminate the intermediate production and subsequent transport of solid copper.