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Copper(II) chloride is used as a catalyst in a variety of processes that produce chlorine by oxychlorination. The Deacon process takes place at about 400 to 450 °C in the presence of a copper chloride: [8] 4 HCl + O 2 → 2 Cl 2 + 2 H 2 O. Copper(II) chloride catalyzes the chlorination in the production of vinyl chloride and dichloromethane. [8]
Dicopper chloride trihydroxide is the compound with chemical formula Cu 2 (O H) 3 Cl. It is often referred to as tribasic copper chloride (TBCC), copper trihydroxyl chloride or copper hydroxychloride. This greenish substance is encountered as the minerals atacamite, paratacamite, and botallackite. [4]
IR absorption spectrum of copper(I) chloride. Copper(I) chloride, commonly called cuprous chloride, is the lower chloride of copper, with the formula CuCl. The substance is a white solid sparingly soluble in water, but very soluble in concentrated hydrochloric acid. Impure samples appear green due to the presence of copper(II) chloride (CuCl 2).
A fifth water resides elsewhere in the framework but does not bind directly to copper. [6] The cobalt chloride mentioned above occurs as [Co(H 2 O) 6] 2+ and Cl −. In tin chloride, each Sn(II) center is pyramidal (mean O/Cl−Sn−O/Cl angle is 83°) being bound to two chloride ions and one water. The second water in the formula unit is ...
The chlorites are the group of phyllosilicate minerals common in low-grade metamorphic rocks and in altered igneous rocks. Greenschist, formed by metamorphism of basalt or other low-silica volcanic rock, typically contains significant amounts of chlorite.
Anthonyite is lavender in color, has a Mohs hardness of 2 and crystallizes in the monoclinic crystal system. Anthonyite occurs as an alteration of native copper in basalt in fractures and cavities by circulation of chloride rich groundwater or connate fluids. The similar orthorhombic mineral calumetite occurs by the same process.
Monoclinic crystal An example of the monoclinic crystal orthoclase. In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic system. They form a parallelogram ...
Copper(II) oxide or cupric oxide is an inorganic compound with the formula CuO. A black solid, it is one of the two stable oxides of copper, the other being Cu 2 O or copper(I) oxide (cuprous oxide). As a mineral, it is known as tenorite, or sometimes black copper.