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Physisorption is a general phenomenon and occurs in any solid/fluid or solid/gas system. Chemisorption is characterized by chemical specificity. In physisorption, perturbation of the electronic states of adsorbent and adsorbate is minimal.
which are the Gibbs energies of physisorption and chemisorption, respectively. Many polymer applications, such as those which use polytetrafluoroethylene (PTFE, or Teflon) require the use of a surface with specific physisorption properties toward one type of material, while being firmly adhered in place to a different type of material.
BET model of multilayer adsorption, that is, a random distribution of sites covered by one, two, three, etc., adsorbate molecules. The concept of the theory is an extension of the Langmuir theory, which is a theory for monolayer molecular adsorption, to multilayer adsorption with the following hypotheses:
Adsorption is present in many natural, physical, biological and chemical systems and is widely used in industrial applications such as heterogeneous catalysts, [9] [10] activated charcoal, capturing and using waste heat to provide cold water for air conditioning and other process requirements (adsorption chillers), synthetic resins, increasing ...
Chemisorption is a kind of adsorption which involves a chemical reaction between the surface and the adsorbate. New chemical bonds are generated at the adsorbent surface. Examples include macroscopic phenomena that can be very obvious, like corrosion [clarification needed], and subtler effects associated with heterogeneous catalysis, where the catalyst and reactants are in different pha
Langmuir was awarded the Nobel Prize in 1932 for his work concerning surface chemistry. He hypothesized that a given surface has a certain number of equivalent sites to which a species can "stick", either by physisorption or chemisorption. His theory began when he postulated that gaseous molecules do not rebound elastically from a surface, but ...
JFK’s grandson Jack Schlossberg’s online trolling does ‘more harm for the Kennedy name than the rest combined’: source
Chemical synthesis using green chemistry promotes the design of new synthetic methods and apparatus that simplify operations and seeks environmentally benign solvents. Key principles include atom economy , which aims to incorporate all reactant atoms into the final product, and the reduction of waste and inefficiencies in chemical processes.
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