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In general, electronegativity increases on passing from left to right along a period and decreases on descending a group. Hence, fluorine is the most electronegative of the elements (not counting noble gases ), whereas caesium is the least electronegative, at least of those elements for which substantial data is available.
On the other hand, electrophilicity generally increases as electronegativity increases, meaning that electrophilicity follows an increasing trend from left to right on the periodic table. [29] However, the specific molecular or chemical environment of the electrophile also influences electrophilicity.
It is more pronounced than the lanthanide contraction because the 5f electrons are less effective at shielding than 4f electrons. [1] It is caused by the poor shielding effect of nuclear charge by the 5f electrons along with the expected periodic trend of increasing electronegativity and nuclear charge on moving from left to right.
Electronegativity is not a uniquely defined property and may depend on the definition. The suggested values are all taken from WebElements as a consistent set. Many of the highly radioactive elements have values that must be predictions or extrapolations, but are unfortunately not marked as such.
Metallic character increases going down a group and from right to left across a period. Nonmetallic character increases going from the bottom left of the periodic table to the top right. The first periodic table to become generally accepted was that of the Russian chemist Dmitri Mendeleev in 1869; he formulated the periodic law as a dependence ...
The lanthanide contraction is the greater-than-expected decrease in atomic radii and ionic radii of the elements in the lanthanide series, from left to right. It is caused by the poor shielding effect of nuclear charge by the 4f electrons along with the expected periodic trend of increasing electronegativity and nuclear charge on moving from left to right.
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See also: Electronegativities of the elements (data page) There are no reliable sources for Pm, Eu and Yb other than the range of 1.1–1.2; see Pauling, Linus (1960).