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Reactions of barium hydroxide with ammonium salts are strongly endothermic. The reaction of barium hydroxide octahydrate with ammonium chloride [18] [19] or [20] ammonium thiocyanate [20] [21] is often used as a classroom chemistry demonstration, producing temperatures cold enough to freeze water and enough water to dissolve the resulting mixture.
Ammonium chloride pyrolyses and reforms into ammonium-chloride smoke after cooling. Ammonium chloride appears to sublime upon heating but actually reversibly decomposes into ammonia and hydrogen chloride gas: [3] NH 4 Cl ⇌ NH 3 + HCl. Ammonium chloride reacts with a strong base, like sodium hydroxide, to release ammonia gas: NH 4 Cl + NaOH ...
For example, the precipitation of silver chloride from a mixture of silver nitrate and cobalt hexammine chloride delivers the nitrate salt of the cobalt complex: 3 AgNO 3 + [Co(NH 3) 6]Cl 3 → 3 AgCl + [Co(NH 3) 6](NO 3) 3. The reactants need not be highly soluble for metathesis reactions to take place.
The formation of barium thiocyanate from ammonium thiocyanate and barium hydroxide is so endothermic that it can freeze a beaker to wet styrofoam. Due to bonds breaking and forming during various processes (changes in state, chemical reactions), there is usually a change in energy.
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
Coloured flames of methanol solutions of different compounds, burning on cotton wool. From left to right: lithium chloride, strontium chloride, calcium chloride, sodium chloride, barium chloride, trimethyl borate, copper chloride, cesium chloride and potassium chloride. Some common elements and their corresponding colors are:
Barium chloride is an inorganic compound with the formula Ba Cl 2. It is one of the most common water-soluble salts of barium . Like most other water-soluble barium salts, it is a white powder, highly toxic, and imparts a yellow-green coloration to a flame.
For example, when barium chloride (BaCl 2) and magnesium sulfate (MgSO 4) react, the SO 4 2− anion switches places with the 2Cl − anion, giving the compounds BaSO 4 and MgCl 2. Another example of a double displacement reaction is the reaction of lead(II) nitrate with potassium iodide to form lead(II) iodide and potassium nitrate : Pb ( NO 3 ...