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This structure is often confused for a body-centered cubic structure because the arrangement of atoms is the same. However, the caesium chloride structure has a basis composed of two different atomic species. In a body-centered cubic structure, there would be translational symmetry along the [111] direction.
This type of structural arrangement is known as cubic close packing (ccp). The unit cell of a ccp arrangement of atoms is the face-centered cubic (fcc) unit cell. This is not immediately obvious as the closely packed layers are parallel to the {111} planes of the fcc unit cell. There are four different orientations of the close-packed layers.
A simple cubic unit cell, with stacks of atoms arranged as if at the eight corners of a cube would form a single cubic hole or void in the center. If these voids are occupied by ions of opposite charge from the parent lattice, the cesium chloride structure is formed.
The Body centered cubic structure (BCC). It is not a close packed structure. In this each metal atom is at the centre of a cube with 8 nearest neighbors, however the 6 atoms at the centres of the adjacent cubes are only approximately 15% further away so the coordination number can therefore be considered to be 14 when these are on one 4 fold ...
I body centered (from the German Innenzentriert) F face centered (from the German Flächenzentriert) A centered on A faces only; B centered on B faces only; C centered on C faces only; R rhombohedral; A reflection plane m within the point groups can be replaced by a glide plane, labeled as a, b, or c depending on which axis the glide is along.
BCC is body centered cubic and FCC is face-centered cubic. Iron-carbon eutectic phase diagram, showing various forms of Fe x C y substances. Iron allotropes, showing the differences in structure. The alpha iron (α-Fe) is a body-centered cubic (BCC) and the gamma iron (γ-Fe) is a face-centered cubic (FCC).
For example, during phonon calculations by the small displacement method, phonon frequencies in crystals are calculated using force values on slightly displaced atoms in the supercell. Another very important example of a supercell is the conventional cell of body-centered (bcc) or face-centered (fcc) cubic crystals.
Equivalently, it is the number of points in a body-centered cubic pattern within a cube that has n + 1 points along each of its edges. The first few centered cube numbers are 1 , 9 , 35 , 91 , 189 , 341, 559, 855, 1241, 1729 , 2331, 3059, 3925, 4941, 6119, 7471, 9009, ...