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  2. Electrochemical cell - Wikipedia

    en.wikipedia.org/wiki/Electrochemical_cell

    An electrolytic cell is an electrochemical cell in which applied electrical energy drives a non-spontaneous redox reaction. [5] A modern electrolytic cell consisting of two half reactions, two electrodes, a salt bridge, voltmeter, and a battery. They are often used to decompose chemical compounds, in a process called electrolysis.

  3. Electrolytic cell - Wikipedia

    en.wikipedia.org/wiki/Electrolytic_cell

    An electrolytic cell is an electrochemical cell that utilizes an external source of electrical energy to force a chemical reaction that would otherwise not occur. [ 1 ] : 64, 89 [ 2 ] : GL7 The external energy source is a voltage applied between the cell's two electrodes ; an anode (positively charged electrode) and a cathode (negatively ...

  4. Galvanic cell - Wikipedia

    en.wikipedia.org/wiki/Galvanic_cell

    In 1799 Volta invented the voltaic pile, which is a stack of galvanic cells each consisting of a metal disk, an electrolyte layer, and a disk of a different metal. He built it entirely out of non-biological material to challenge Galvani's (and the later experimenter Leopoldo Nobili )'s animal electricity theory in favor of his own metal-metal ...

  5. Electrochemistry - Wikipedia

    en.wikipedia.org/wiki/Electrochemistry

    The decomposition of water into hydrogen and oxygen can be performed in an electrolytic cell. In it, a pair of inert electrodes usually made of platinum immersed in water act as anode and cathode in the electrolytic process. The electrolysis starts with the application of an external voltage between the electrodes.

  6. Electrode potential - Wikipedia

    en.wikipedia.org/wiki/Electrode_potential

    It may also be defined as the potential difference between the charged metallic rods and salt solution. The electrode potential has its origin in the potential difference developed at the interface between the electrode and the electrolyte. It is common, for instance, to speak of the electrode potential of the M + /M redox couple.

  7. Overpotential - Wikipedia

    en.wikipedia.org/wiki/Overpotential

    In electrochemistry, overpotential is the potential difference between a half-reaction's thermodynamically determined reduction potential and the potential at which the redox event is experimentally observed. [1] The term is directly related to a cell's voltage efficiency.

  8. Electrolyte - Wikipedia

    en.wikipedia.org/wiki/Electrolyte

    Electrolytic conductors are used in electronic devices where the chemical reaction at a metal-electrolyte interface yields useful effects. In batteries , two materials with different electron affinities are used as electrodes; electrons flow from one electrode to the other outside of the battery, while inside the battery the circuit is closed ...

  9. Half-cell - Wikipedia

    en.wikipedia.org/wiki/Half-cell

    The electrochemical series, which consists of standard electrode potentials and is closely related to the reactivity series, was generated by measuring the difference in potential between the metal half-cell in a circuit with a standard hydrogen half-cell, connected by a salt bridge. The standard hydrogen half-cell: 2H + (aq) + 2e − → H 2 (g)