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The specific enthalpy of fusion (more commonly known as latent heat) of water is 333.55 kJ/kg at 0 °C: the same amount of energy is required to melt ice as to warm ice from −160 °C up to its melting point or to heat the same amount of water by about 80 °C. Of common substances, only that of ammonia is higher.
The terms sensible heat and latent heat refer to energy transferred between a body and its surroundings, defined by the occurrence or non-occurrence of temperature change; they depend on the properties of the body. Sensible heat is sensed or felt in a process as a change in the body's temperature.
Enthalpies of melting and boiling for pure elements versus temperatures of transition, demonstrating Trouton's rule. In thermodynamics, the enthalpy of fusion of a substance, also known as (latent) heat of fusion, is the change in its enthalpy resulting from providing energy, typically heat, to a specific quantity of the substance to change its state from a solid to a liquid, at constant pressure.
Temperature-dependency of the heats of vaporization for water, methanol, benzene, and acetone. In thermodynamics, the enthalpy of vaporization (symbol ∆H vap), also known as the (latent) heat of vaporization or heat of evaporation, is the amount of energy that must be added to a liquid substance to transform a quantity of that substance into a gas.
J.A. Dean (ed), Lange's Handbook of Chemistry (15th Edition), McGraw-Hill, 1999; Section 6, Thermodynamic Properties; Table 6.4, Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of the Elements and Inorganic Compounds
Regardless of the equation format, the heat of formation of a compound at any temperature is ΔH° form at 298.15 K, plus the sum of the heat content parameters of the products minus the sum of the heat content parameters of the reactants. The C p equation is obtained by taking the derivative of the heat content equation.
This is accomplished by solving heat equations in both regions, subject to given boundary and initial conditions. At the interface between the phases (in the classical problem) the temperature is set to the phase change temperature. To close the mathematical system a further equation, the Stefan condition, is required. This is an energy balance ...
For example, the entropies of vaporization of water, ethanol, formic acid and hydrogen fluoride are far from the predicted values. The entropy of vaporization of XeF 6 at its boiling point has the extraordinarily high value of 136.9 J/(K·mol). [ 4 ]