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Bromoform was discovered in 1832 by Löwig who distilled a mixture of bromal and potassium hydroxide, as analogous to preparation of chloroform from chloral. [5]Bromoform can be prepared by the haloform reaction using acetone and sodium hypobromite, by the electrolysis of potassium bromide in ethanol, or by treating chloroform with aluminium bromide.
Bromoform, produced by several algae, is a known toxin, though the small amounts present in edible algae do not appear to pose human harm. [12] Some of these organobromine compounds are employed in a form of interspecies "chemical warfare".
The EPA limits the total concentration of the four chief constituents (chloroform, bromoform, bromodichloromethane, and dibromochloromethane), referred to as total trihalomethanes (TTHM), to 80 parts per billion in treated water. [6] Traces of chloroform are produced in swimming pools. [7] [8] [9] [10]
Bromomethane, commonly known as methyl bromide, is an organobromine compound with formula C H 3 Br.This colorless, odorless, nonflammable gas is produced both industrially and biologically.
In 1847, Scottish obstetrician James Y. Simpson was the first to demonstrate the anaesthetic properties of chloroform in humans, provided by local pharmacist William Flockhart of Duncan, Flockhart and company, [28] and helped to popularize the drug for use in medicine. [29] By the 1850s, chloroform was being produced on a commercial basis.
Bromoacetone is available commercially, sometimes stabilized with magnesium oxide.It was first described in the 19th century, attributed to N. Sokolowsky. [3]Acetone and bromine form bromoacetone.
Bromodichloromethane is a trihalomethane with formula C H Br Cl 2.It is a colorless, nonflammable liquid which will dissolve in water, or evaporate in air. [1] Most of the chemical is produced through the chlorine disinfection process, [1] and as a result it can occur in municipally-treated drinking water. [2]
The term creosote has a broad range of definitions depending on the origin of the coal tar oil and end-use of the material. With respect to wood preservatives, the United States Environmental Protection Agency (EPA) considers the term creosote to mean a pesticide for use as a wood preservative meeting the American Wood Protection Association (AWPA) Standards P1/P13 and P2. [6]