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Half reactions are often used as a method of balancing redox reactions. For oxidation-reduction reactions in acidic conditions, after balancing the atoms and oxidation numbers, one will need to add H + ions to balance the hydrogen ions in the half reaction.
The reacting redox species do not have to be necessarily adjacent on a Frost diagram. The comproportionation reaction cannot easily occur in solids in which the potentially reactive species are immobile and thus cannot react together, or the reaction will be extremely slow and will also require high temperature close to the melting point of the ...
The increase in the oxidation state of an atom, through a chemical reaction, is known as oxidation; a decrease in oxidation state is known as a reduction. Such reactions involve the formal transfer of electrons: a net gain in electrons being a reduction, and a net loss of electrons being oxidation. For pure elements, the oxidation state is zero.
Electron transfer reactions are central to myriad processes and properties in soils, and redox potential, quantified as Eh (platinum electrode potential relative to the standard hydrogen electrode) or pe (analogous to pH as -log electron activity), is a master variable, along with pH, that controls and is governed by chemical reactions and ...
Illustration of a redox reaction Sodium chloride is formed through the redox reaction of sodium metal and chlorine gas. Redox reactions can be understood in terms of the transfer of electrons from one involved species (reducing agent) to another (oxidizing agent). In this process, the former species is oxidized and the latter is reduced. Though ...
The chain of redox reactions driving the flow of electrons through the electron transport chain, from electron donors such as NADH to electron acceptors such as oxygen and hydrogen (protons), is an exergonic process – it releases energy, whereas the synthesis of ATP is an endergonic process, which requires an input of energy.
In contrast, some authors use the term redistribution to refer to reactions of this type (in either direction) when only ligand exchange but no redox is involved and distinguish such processes from disproportionation and comproportionation. For example, the Schlenk equilibrium. 2 RMgX → R 2 Mg + MgX 2. is an example of a redistribution reaction.
An atom (or ion) whose oxidation number increases in a redox reaction is said to be oxidized (and is called a reducing agent). It is accomplished by loss of one or more electrons. The atom whose oxidation number decreases gains (receives) one or more electrons and is said to be reduced. This relation can be remembered by the following mnemonics.