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Triatomic oxygen (ozone, O 3) is a very reactive allotrope of oxygen that is a pale blue gas at standard temperature and pressure. Liquid and solid O 3 have a deeper blue color than ordinary O 2, and they are unstable and explosive. [5] [6] In its gas phase, ozone is destructive to materials like rubber and fabric and is damaging to lung tissue ...
Ozone in the stratosphere is mostly produced from short-wave ultraviolet rays between 240 and 160 nm. Oxygen starts to absorb weakly at 240 nm in the Herzberg bands, but most of the oxygen is dissociated by absorption in the strong Schumann–Runge bands between 200 and 160 nm where ozone does not absorb. While shorter wavelength light ...
Ozone-oxygen cycle in the ozone layer. The photochemical mechanisms that give rise to the ozone layer were discovered by the British physicist Sydney Chapman in 1930. Ozone in the Earth's stratosphere is created by ultraviolet light striking ordinary oxygen molecules containing two oxygen atoms (O 2), splitting them into individual oxygen atoms (atomic oxygen); the atomic oxygen then combines ...
Oxygen photolyzed to atomic oxygen 2. Oxygen and ozone continuously interconverted. Solar UV breaks down oxygen; molecular and atomic oxygen combine to form Ozone. 3. Ozone is lost by reaction with atomic oxygen (plus other trace atoms). The ozone–oxygen cycle is the process by which ozone is continually regenerated in Earth's stratosphere ...
Oxygen is the third most abundant chemical element in the universe, after hydrogen and helium. [68] About 0.9% of the Sun's mass is oxygen. [19] Oxygen constitutes 49.2% of the Earth's crust by mass [69] as part of oxide compounds such as silicon dioxide and is the most abundant element by mass in the Earth's crust.
Homonuclear diatomic molecules include hydrogen (H 2), oxygen (O 2), nitrogen (N 2) and all of the halogens. Ozone (O 3) is a common triatomic homonuclear molecule. Homonuclear tetratomic molecules include arsenic (As 4) and phosphorus (P 4).
Three forms (or allotropes) of oxygen are involved in the ozone-oxygen cycle: oxygen atoms (O or atomic oxygen), oxygen gas (O 2 or diatomic oxygen), and ozone gas (O 3 or triatomic oxygen). [15] Ozone is formed in the stratosphere when oxygen gas molecules photodissociate after absorbing UVC photons. This converts a single O
The energy difference of 94.3 kJ/mol between ground state and singlet oxygen corresponds to a forbidden singlet-triplet transition in the near-infrared at ~1270 nm. [12] As a consequence, singlet oxygen in the gas phase is relatively long lived (54-86 milliseconds), [ 13 ] although interaction with solvents reduces the lifetime to microseconds ...