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Oxygen and ozone continuously interconverted. Solar UV breaks down oxygen; molecular and atomic oxygen combine to form Ozone. 3. Ozone is lost by reaction with atomic oxygen (plus other trace atoms). The ozone–oxygen cycle is the process by which ozone is continually regenerated in Earth's stratosphere, converting ultraviolet radiation (UV ...
The ozone layer visible from space at Earth's horizon as a blue band of afterglow within the bottom of the large bright blue band that is the stratosphere, with a silhouette of a cumulonimbus in the orange afterglow of the troposphere. The ozone layer or ozone shield is a region of Earth's stratosphere that absorbs most of the Sun's ultraviolet ...
Ozone in the ozone layer filters out sunlight wavelengths from about 200 nm UV rays to 315 nm, with ozone peak absorption at about 250 nm. [55] This ozone UV absorption is important to life, since it extends the absorption of UV by ordinary oxygen and nitrogen in air (which absorb all wavelengths < 200 nm) through the lower UV-C (200–280 nm ...
The formation of the ozone layer is also caused by photodissociation. Ozone in the Earth's stratosphere is created by ultraviolet light striking oxygen molecules containing two oxygen atoms (O 2), splitting them into individual oxygen atoms (atomic oxygen). The atomic oxygen then combines with unbroken O 2 to create ozone, O 3. [17]
Medium-wave UV, mostly absorbed by the ozone layer: intermediate UV; Dorno radiation. UVB 280–315 Ultraviolet C 4.43–12.4 0.710–1.987 Short-wave UV, germicidal UV, ionizing radiation at shorter wavelengths, completely absorbed by the ozone layer and atmosphere: hard UV. UVC 100–280 Near ultraviolet 3.10–4.13 0.497–0.662
Ozone absorbs strongly in the ultraviolet and in the stratosphere functions as a shield for the biosphere against mutagenic and other damaging effects of solar UV radiation (see ozone layer). [5] Tropospheric ozone is formed near the Earth's surface by the photochemical disintegration of nitrogen dioxide in the exhaust of automobiles. [10]
The mechanism describing the formation of the ozone layer was described by British mathematician and geophysicist Sydney Chapman in 1930, and is known as the Chapman cycle or ozone–oxygen cycle. [8] Molecular oxygen absorbs high energy sunlight in the UV-C region, at wavelengths shorter than about 240 nm. Radicals produced from the ...
The short wavelength boundary of the atmospheric IR window is set by absorption in the lowest frequency vibrational bands of water vapor. There is a strong band of ozone at 9.6 μm in the middle of the window which is why it acts as such a strong greenhouse gas. Water vapor has a continuum absorption due to collisional broadening of absorption ...