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The process may be likened to how yeast ferments sugars to produce ethanol for wine, beer, or fuel, but the organisms that carry out the ABE fermentation are strictly anaerobic (obligate anaerobes). The ABE fermentation produces solvents in a ratio of 3 parts acetone, 6 parts butanol to 1 part ethanol.
Solventogenesis is the biochemical production of solvents (usually acetone and butanol) by Clostridium species. [1] It is the second phase of ABE fermentation. [2] This figure shows acidogenic and solventogenic phases of ABE fermentation by solventogenic Clostridium species.
The method has been described since as the ABE process, (Acetone Butanol Ethanol fermentation process), yielding 3 parts of acetone, 6 of n-butanol, and 1 of ethanol. Acetone was used in the important wartime task of casting cordite. The alcohols were used to produce vehicle fuels and synthetic rubber.
A disadvantage is that it produces relatively little ATP, yielding only between 2 and 4.5 per glucose [1] compared to 32 for aerobic respiration. [8] Over 25% of bacteria and archaea carry out fermentation. [2] [3] This type of metabolism is most common in the phylum Bacillota, and it is least common in Actinomycetota. [2]
2-methyl-1-butanol - sometimes called "active" amyl alcohol; isobutyl alcohol - one of the least toxic of the butanols. 1-propanol; Other higher alcohols that can be produced during fermentation include: isopropanol (isopropyl alcohol), oxidized to form acetone by alcohol dehydrogenase in the liver, leading to ketosis when ingested in large ...
The original 1899 publication concerned the conversion of n-butanol to 2-ethylhexanol. [2] 2-ethylhexanol is however more easily prepared by alternative methods (from butyraldehyde by aldol condensation). Instead, the Guerbet reaction is mainly applied to fatty alcohols to afford oily products, which are called Guerbet alcohols. They are of ...
The production of acetone by acetoacetate decarboxylase-containing or clostridial bacteria was utilized in large-scale industrial syntheses in the first half of the twentieth century. In the 1960s, the industry replaced this process with less expensive, more efficient chemical syntheses of acetone from petroleum and petroleum derivatives. [6]
He developed the acetone–butanol–ethanol fermentation process, which produces acetone, n-butanol and ethanol through bacterial fermentation. His acetone production method was of great importance in the manufacture of cordite explosive propellants for the British war industry during World War I .