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where is the volume of the pure solvent before adding the solute and ~ its molar volume (at the same temperature and pressure as the solution), is the number of moles of solvent, ~ is the apparent molar volume of the solute, and is the number of moles of the solute in the solution. By dividing this ...
The ideal gas equation can be rearranged to give an expression for the molar volume of an ideal gas: = = Hence, for a given temperature and pressure, the molar volume is the same for all ideal gases and is based on the gas constant: R = 8.314 462 618 153 24 m 3 ⋅Pa⋅K −1 ⋅mol −1, or about 8.205 736 608 095 96 × 10 −5 m 3 ⋅atm⋅K ...
For a substance X with a specific volume of 0.657 cm 3 /g and a substance Y with a specific volume 0.374 cm 3 /g, the density of each substance can be found by taking the inverse of the specific volume; therefore, substance X has a density of 1.522 g/cm 3 and substance Y has a density of 2.673 g/cm 3. With this information, the specific ...
The PSV is usually measured in milliLiters (mL) per gram (g), proteins > 30 kDa can be assumed to have a partial specific volume of 0.708 mL/g. [1] Experimental determination is possible by measuring the natural frequency of a U-shaped tube filled successively with air, buffer and protein solution.
The steady-state heat equation for a volume that contains a heat source (the inhomogeneous case), is the Poisson's equation: − k ∇ 2 u = q {\displaystyle -k\nabla ^{2}u=q} where u is the temperature , k is the thermal conductivity and q is the rate of heat generation per unit volume.
The equation modifies the ideal gas law in two ways: first, it considers particles to have a finite diameter (whereas an ideal gas consists of point particles); second, its particles interact with each other (unlike an ideal gas, whose particles move as though alone in the volume). The equation is named after Dutch physicist Johannes Diderik ...
Theoretical chemistry requires quantities from core physics, such as time, volume, temperature, and pressure.But the highly quantitative nature of physical chemistry, in a more specialized way than core physics, uses molar amounts of substance rather than simply counting numbers; this leads to the specialized definitions in this article.
The van der Waals equation of state may be written as (+) =where is the absolute temperature, is the pressure, is the molar volume and is the universal gas constant.Note that = /, where is the volume, and = /, where is the number of moles, is the number of particles, and is the Avogadro constant.