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Gas stoichiometry is the quantitative relationship (ratio) between reactants and products in a chemical reaction with reactions that produce gases. Gas stoichiometry applies when the gases produced are assumed to be ideal, and the temperature, pressure, and volume of the gases are all known. The ideal gas law is used for these calculations.
Typically, non-compressible fluids are used with no gas volume so that the expansion factor as a function of pressure is small. Mixing can be achieved within seconds at the smaller scales used in flow chemistry. Heat transfer is intensified. Mostly, because the area to volume ratio is large.
For his 1934 paper, Alfred Redfield analyzed nitrate and phosphate data for the Atlantic, Indian, Pacific oceans and Barents Sea. [1] As a Harvard physiologist, Redfield participated in several voyages on board the research vessel Atlantis, analyzing data for C, N, and P content in marine plankton, and referenced data collected by other researchers as early as 1898.
where w C, w H, w S, w O refer to the mass fraction of each element in the fuel oil, sulfur burning to SO 2, and AFR mass refers to the air-fuel ratio in mass units. For 1 kg of fuel oil containing 86.1% C, 13.6% H, 0.2% O, and 0.1% S the stoichiometric mass of air is 14.56 kg, so AFR = 14.56. The combustion product mass is then 15.56 kg.
Most work in ecological stoichiometry focuses on the interface between an organism and its resources. This interface, whether it is between plants and their nutrient resources or large herbivores and grasses, is often characterized by dramatic differences in the elemental composition of each part. The difference, or mismatch, between the ...
Air–fuel equivalence ratio, λ (lambda), is the ratio of actual AFR to stoichiometry for a given mixture. λ = 1.0 is at stoichiometry, rich mixtures λ < 1.0, and lean mixtures λ > 1.0. There is a direct relationship between λ and AFR. To calculate AFR from a given λ, multiply the measured λ by the stoichiometric AFR for that fuel.
Intermetallics are generally hard and brittle, with good high-temperature mechanical properties. [1] [2] [3] They can be classified as stoichiometric or nonstoichiometic. [1] The term "intermetallic compounds" applied to solid phases has long been in use.
Periodic Videos (also known as The Periodic Table of Videos) is a video project and YouTube channel on chemistry. It consists of a series of videos about chemical elements and the periodic table , with additional videos on other topics in chemistry and related fields.