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Sodium polysulfide can be produced by dissolving sulfur in a solution of sodium sulfide. [4] Alternatively they are produced by the redox reaction of aqueous sodium hydroxide with sulfur at elevated temperatures. [5] Finally they arise by the reduction of elemental sulfur with sodium, a reaction often conducted in anhydrous ammonia.
It is slightly soluble in water and acts as a weak acid (pK a = 6.9 in 0.01–0.1 mol/litre solutions at 18 °C), giving the hydrosulfide ion HS −. Hydrogen sulfide and its solutions are colorless. When exposed to air, it slowly oxidizes to form elemental sulfur, which is not soluble in water. The sulfide anion S 2− is not formed in aqueous ...
Treatment of sulfur with hydrogen gives hydrogen sulfide.When dissolved in water, hydrogen sulfide is mildly acidic: [5] H 2 S ⇌ HS − + H +. Hydrogen sulfide gas and the hydrosulfide anion are extremely toxic to mammals, due to their inhibition of the oxygen-carrying capacity of hemoglobin and certain cytochromes in a manner analogous to cyanide and azide.
It is produced through the reaction between elemental sulfur and sodium hydrosulfide in alcoholic solution: [3] 2NaSH + 4 S → Na 2 S 4 + H 2 S. The polysulfide anions adopt zig-zag chains of sulfur atoms. The S-S distances are about 2.05 Å and the S-S-S-S dihedral angles are around 90°. [4]
The alkali metal polysulfides arise by treatment of a solution of the sulfide with elemental sulfur, e.g. sodium sulfide to sodium polysulfide: S 2− + n S → S 2− n+1. In some cases, these anions have been obtained as organic salts, which are soluble in organic solvents. [4]
Sulfide (also sulphide in British English) [2] is an inorganic anion of sulfur with the chemical formula S 2− or a compound containing one or more S 2− ions. Solutions of sulfide salts are corrosive. Sulfide also refers to large families of inorganic and organic compounds, e.g. lead sulfide and dimethyl sulfide.
Oxidizing silver with liver of sulfur solution. Liver of sulfur is a loosely defined mixture of potassium sulfide, potassium polysulfide, potassium thiosulfate, and likely potassium bisulfide. Synonyms include hepar sulfuris, sulfur, sulfurated potash and sulfurated potassa. There are two distinct varieties: "potassic liver of sulfur" and ...
Phosphorus sulfides comprise a family of inorganic compounds containing only phosphorus and sulfur.These compounds have the formula P 4 S n with n ≤ 10. Two are of commercial significance, phosphorus pentasulfide (P 4 S 10), which is made on a kiloton scale for the production of other organosulfur compounds, and phosphorus sesquisulfide (P 4 S 3), used in the production of "strike anywhere ...