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In carbohydrate chemistry, a pair of anomers (from Greek ἄνω 'up, above' and μέρος 'part') is a pair of near-identical stereoisomers or diastereomers that differ at only the anomeric carbon, the carbon atom that bears the aldehyde or ketone functional group in the sugar's open-chain form.
The system of carbohydrate representation was adopted and widely disseminated by many including the NIGMS-funded Consortium for Functional Glycomics, and thus was often referred to as "CFG Nomenclature". This color representation was vastly expanded in the third edition of the text to include 49 new monosaccharides that appear mostly in non ...
Glycosylation is the reaction in which a carbohydrate (or 'glycan'), i.e. a glycosyl donor, is attached to a hydroxyl or other functional group of another molecule (a glycosyl acceptor) in order to form a glycoconjugate.
Lectins, or proteins that bind carbohydrates, can recognize specific oligosaccharides and provide useful information for cell recognition based on oligosaccharide binding. [ citation needed ] An important example of oligosaccharide cell recognition is the role of glycolipids in determining blood types .
Carbochemistry is the branch of chemistry that studies the transformation of coal (bituminous coal, coal tar, anthracite, lignite, graphite, and charcoal) into useful products and raw materials. [1] The processes that are used in carbochemistry include degasification processes such as carbonization and coking , gasification processes, and ...
Generally, the carbohydrate part(s) play an integral role in the function of a glycoconjugate; prominent examples of this are neural cell adhesion molecule (NCAM) and blood proteins where fine details in the carbohydrate structure determine cell binding (or not) or lifetime in circulation.
The chair conformation of six-membered rings have a dihedral angle of 60° between adjacent substituents thus usually making it the most stable conformer. Since there are two possible chair conformation steric and stereoelectronic effects such as the anomeric effect, 1,3-diaxial interactions, dipoles and intramolecular hydrogen bonding must be taken into consideration when looking at relative ...
Carbohydrate synthesis is a sub-field of organic chemistry concerned with generating complex carbohydrate structures from simple units (monosaccharides). The generation of carbohydrate structures usually involves linking monosaccharides or oligosaccharides through glycosidic bonds, a process called glycosylation .