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In organic chemistry, a sulfide (British English sulphide) or thioether is an organosulfur functional group with the connectivity R−S−R' as shown on right. Like many other sulfur-containing compounds, volatile sulfides have foul odors. [1] A sulfide is similar to an ether except that it contains
Sulfide (also sulphide in British English) [2] is an inorganic anion of sulfur with the chemical formula S 2− or a compound containing one or more S 2− ions. Solutions of sulfide salts are corrosive. Sulfide also refers to large families of inorganic and organic compounds, e.g. lead sulfide and dimethyl sulfide.
[15] [16] The term "methyl" was derived in about 1840 by back-formation from "methylene", and was then applied to describe "methyl alcohol" (which since 1892 is called "methanol"). Methyl is the IUPAC nomenclature of organic chemistry term for an alkane (or alkyl) molecule, using the prefix "meth-" to indicate the presence of a single carbon.
Sulfonyl groups can be reduced to the sulfide with diisobutylaluminium hydride (DIBALH). Lithium aluminium hydride (LiAlH 4) reduces some but not all sulfones to sulfides. [1]: 1851 In inorganic chemistry, when the group −S(=O) 2 − is not connected to any carbon atoms, it is referred to as sulfuryl. [3]
Dimethyl sulfide, dimethyl disulfide, and dimethyl trisulfide have been found among the volatiles given off by the fly-attracting plant known as dead-horse arum (Helicodiceros muscivorus). Those compounds are components of an odor like rotting meat, which attracts various pollinators that feed on carrion, such as many species of flies. [17]
The compound (C 5 H 5) 2 TiS 5 is an example of a polysulfide complex. Polysulfides are a class of chemical compounds derived from anionic chains of sulfur atoms. [1] There are two main classes of polysulfides: inorganic and organic. The inorganic polysulfides have the general formula S 2− n. These anions are the conjugate bases of ...
Allyl methyl sulfide is an organosulfur compound with the chemical formula CH 2 =CHCH 2 SCH 3. The molecule features two functional groups, an allyl (CH 2 =CHCH 2) and a sulfide. It is a colourless liquid with a strong odor characteristic of alkyl sulfides. It is a metabolite of garlic, and "garlic breath" is attributed to its presence. [1]
Also acid ionization constant or acidity constant. A quantitative measure of the strength of an acid in solution expressed as an equilibrium constant for a chemical dissociation reaction in the context of acid-base reactions. It is often given as its base-10 cologarithm, p K a. acid–base extraction A chemical reaction in which chemical species are separated from other acids and bases. acid ...