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  2. Sulfur tetrafluoride - Wikipedia

    en.wikipedia.org/wiki/Sulfur_tetrafluoride

    Sulfur tetrafluoride is a chemical compound with the formula S F 4. It is a colorless corrosive gas that releases dangerous hydrogen fluoride gas upon exposure to water or moisture. Sulfur tetrafluoride is a useful reagent for the preparation of organofluorine compounds , [ 3 ] some of which are important in the pharmaceutical and specialty ...

  3. Three-center four-electron bond - Wikipedia

    en.wikipedia.org/wiki/Three-center_four-electron...

    The 3-center 4-electron (3c–4e) bond is a model used to explain bonding in certain hypervalent molecules such as tetratomic and hexatomic interhalogen compounds, sulfur tetrafluoride, the xenon fluorides, and the bifluoride ion.

  4. Seesaw molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Seesaw_molecular_geometry

    The seesaw geometry occurs when a molecule has a steric number of 5, with the central atom being bonded to 4 other atoms and 1 lone pair (AX 4 E 1 in AXE notation). An atom bonded to 5 other atoms (and no lone pairs) forms a trigonal bipyramid with two axial and three equatorial positions, but in the seesaw geometry one of the atoms is replaced ...

  5. VSEPR theory - Wikipedia

    en.wikipedia.org/wiki/VSEPR_theory

    Valence shell electron pair repulsion (VSEPR) theory (/ ˈ v ɛ s p ər, v ə ˈ s ɛ p ər / VESP-ər, [1]: 410 və-SEP-ər [2]) is a model used in chemistry to predict the geometry of individual molecules from the number of electron pairs surrounding their central atoms. [3]

  6. Thionyl tetrafluoride - Wikipedia

    en.wikipedia.org/wiki/Thionyl_tetrafluoride

    Thionyl tetrafluoride, also known as sulfur tetrafluoride oxide, is an inorganic compound with the formula S O F 4. It is a colorless gas. The shape of the molecule is a distorted trigonal bipyramid, with the oxygen found on the equator. The atoms on the equator have shorter bond lengths than the fluorine atoms on the axis.

  7. Spartan (chemistry software) - Wikipedia

    en.wikipedia.org/wiki/Spartan_(chemistry_software)

    Spartan is a molecular modelling and computational chemistry application from Wavefunction. [2] It contains code for molecular mechanics, semi-empirical methods, ab initio models, [3] density functional models, [4] post-Hartree–Fock models, [5] and thermochemical recipes including G3(MP2) [6] and T1. [7]

  8. Thionyl fluoride - Wikipedia

    en.wikipedia.org/wiki/Thionyl_fluoride

    This colourless gas is mainly of theoretical interest, but it is a product of the degradation of sulfur hexafluoride, an insulator in electrical equipment. The molecule adopts a distorted pyramidal structure, with C s symmetry. The S-O and S-F distances are 1.42 and 1.58 Å, respectively. The O-S-F and F-S-F angles are 106.2 and 92.2 ...

  9. Trigonal bipyramidal molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Trigonal_bipyramidal...

    The seesaw molecular geometry is found in sulfur tetrafluoride (SF 4) with a central sulfur atom surrounded by four fluorine atoms occupying two axial and two equatorial positions, as well as one equatorial lone pair, corresponding to an AX 4 E molecule in the AXE notation.