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Earliest known written formula for gunpowder, from the Wujing Zongyao of 1044 AD.. Gunpowder is the first explosive to have been developed. Popularly listed as one of the "Four Great Inventions" of China, it was invented during the late Tang dynasty (9th century) while the earliest recorded chemical formula for gunpowder dates to the Song dynasty (11th century).
The earliest gunpowder recipe and primitive weaponry date to China's Song dynasty and the oldest extant guns appear in the Mongol-led Yuan dynasty of China. However, historian Tonio Andrade notes that there is a surprising scarcity of reliable evidence of firearms in Iran or Central Asia prior to the late 14th century.
China: Private trade of gunpowder ingredients is banned in the Song dynasty. [20] 1075: Sinosphere: Vietnam's Lý dynasty used fire arrows and against the Song dynasty during the Lý–Song War (1075–1077). [21] 1076: China: Trade of gunpowder ingredients with the Liao and Western Xia dynasties is outlawed by the Song court. [14] 1083: China
These four discoveries had an enormous impact on the development of Chinese civilization and a far-ranging global impact. Gunpowder, for example, spread to the Arabs in the 13th century and thence to Europe. [21] According to English philosopher Francis Bacon, writing in Novum Organum:
Gunpowder was invented in the 9th century by Chinese alchemists searching for an elixir of immortality. [19] By the time the Song dynasty treatise, Wujing Zongyao (武经总要), was written by Zeng Gongliang and Yang Weide in 1044, the various Chinese formulas for gunpowder held levels of nitrate in the range of 27% to 50%. [20]
The first confirmed reference to what can be considered gunpowder in China occurred during the Tang dynasty, first in a formula contained in the Taishang Shengzu Jindan Mijue (太上聖祖金丹秘訣) in 808, and then about 50 years later in a Taoist text known as the Zhenyuan miaodao yaolüe (真元妙道要略). [20]
The recorded military history of China extends from about 2200 BC to the present day. Chinese pioneered the use of crossbows, advanced metallurgical standardization for arms and armor, early gunpowder weapons, and other advanced weapons, but also adopted nomadic cavalry [1] and Western military technology. [2]
Upon impact, the huoqiu would start a fire among an invading army. [28] Chinese bombs such as the thunder clap bomb or pili pao used a greater percentage of gunpowder than that of the huoqiu. The gunpowder mixture for a bomb was placed within a rigid container that held in the expanding gas, allowing for more powerful explosions.